Fast pyrolysis of holocellulose for the preparation of long-chain ether fuel precursors: Effect of holocellulose types

The pyrolysis behaviors of nine biomass-derived holocelluloses (from seven agricultural and two forestry residues) were studied on a thermogravimetric analyzer (TGA) and pyrolysis-gas chromatography/mass spectrometer (Py-GC/MS). The results illustrated that compared with forestry holocellulose, agricultural holocellulose had quite high ash and hemicellulose contents. Moreover, agricultural holocellulose presented lower initial temperature and maximum mass loss rate. The results of GC/MS revealed that agricultural holocellulose produced more acids, ketones, aldehydes and furans and corn stalk holocellulose led to the highest targeted compounds (ketones, aldehydes and furans with carbonyl group) content of 51.4%. Woody holocellulose was suitable for the production of sugars, particularly levoglucosan, and pine sawdust holocellulose afforded the highest levoglucosan content of 46.55%. Intriguingly, the correlation of sugars/levoglucosan content with a mass ratio of cellulose to hemicellulose (CE/HCE) was put forward.

Automated summary

The study compared the pyrolysis behaviors of agricultural and forestry residues' holocelluloses and found that agricultural holocellulose contains higher ash and hemicellulose content, with lower initial temperature and maximum mass loss rate compared to forestry holocellulose. Agricultural holocellulose produced more acids, ketones, aldehydes, and furans, while corn stalk holocellulose had the highest content of targeted compounds. Woody and pine sawdust holocelluloses were suitable for producing sugars like levoglucosan.