期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 18, 期 -, 页码 217-224出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.18.25
关键词
enantioselective; malonamate; nitroso aldol reaction; N-selectivity; Takemoto catalyst
资金
- CSIR-New Delhi
- UGC-New Delhi
The practical enantioselective N-selective nitroso aldol reaction of alpha-methylmalonamates with a nitrosoarene is reported. The Takemoto thiourea catalyst was employed to induce enantioselectivity, leading to the formation of optically active oxyaminated malonamates in reasonably good yields.
A practical enantioselective N-selective nitroso aldol reaction of alpha-methylmalonamates with a nitrosoarene is reported. The reaction employs the Takemoto thiourea catalyst for the induction of enantioselectivity, and the corresponding optically active oxyaminated malonamates were obtained in reasonably good yields.
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