4.7 Article

Enhanced oxidation resistance of Mo-modified Si-SiC coating on C/C composites by laser-inducing

期刊

APPLIED SURFACE SCIENCE
卷 575, 期 -, 页码 -

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ELSEVIER
DOI: 10.1016/j.apsusc.2021.151786

关键词

Laser; Modification; Oxidation; Coating repair; C/C composites

资金

  1. National Natural Science Founda-tions of China [51772247, 51727804, 91860203]
  2. Creative Research Foundation of Science and Technology on Thermo-structural Composite Materials Laboratory [JCKYS2019607002]

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In this study, a Mo-modified Si-SiC coating was prepared by laser-inducing to repair damaged SiC coated C/C composites. The modified coating showed improved interface bonding and self-healing ability, resulting in a significant reduction in mass loss after oxidation compared to the untreated damaged sample.
As the thermal structural component of aircraft, SiC coated C/C composites will fail and cause catastrophic consequences once the SiC anti-oxidation coating is damaged. Therefore, it is extremely important to develop a coating repair system with excellent oxidation protection performance. In this study, a Mo-modified Si-SiC coating was prepared by laser-inducing to repair the damaged SiC coated C/C composites. Thermal shock test between room temperature and 1773 K was conducted to study the interface bonding and 1773 K cyclic oxidation test was performed to examine the repair effect. With 10 wt% Mo-modification by laser-inducing, MoSi2 precipitated at the interfaces while the interface bonding was not weaken. The decreased free Si, densified structure of coating and enhanced self-healing ability, which were obtained by modifying, contributed to reduce the mass loss after oxidation by similar to 70% compared with the damaged sample without repairing.

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