4.7 Article

Atmospheric pressure plasma engineered superhydrophilic CuO surfaces with enhanced catalytic activities

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Cu2O/CuO heterojunction catalysts through atmospheric pressure plasma induced defect passivation

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Summary: A novel method using atmospheric pressure plasma jet (APPJ) was demonstrated to fabricate Cu2 0/CuO heterojunction electrodes with favorable band alignment, producing nanoscale CuO surface features with low density of interfacial defects. The electrode showed remarkable performance in oxygen evolution reaction (OER) and photocatalytic hydrogen evolution reaction (HER). The electronic structure modeling revealed shifts in band centers at the interface, contributing to increased catalytic activity of the heterostructure. The study highlighted the potential of APPJ functionalization in tuning surface electronic properties of copper oxide catalysts for enhanced efficiency in OER and HER water splitting.

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