Minimizing lattice thermal conductivity is crucial for improving thermoelectric performance, with alloying being a common method. Research shows that lattice thermal conductivity of most materials can be further reduced, and materials with good electrical performance exhibit high power factors in their operating temperature ranges.
Minimizing the lattice thermal conductivity of thermoelectric materials is essential for preserving the temperature difference during the operation of thermoelectric devices incorporating these materials. During the past two decades, there has been substantial improvement in the thermoelectric figure of merit (zT) due to reduced lattice thermal conductivity. Employing alloying effects in solid-solution compounds is the most common and practical approach for inhibiting lattice thermal conductivity. This Perspective takes the n-type Mg3Sb2-xBix thermoelectric alloys as examples, addressing their lattice thermal conductivity and corresponding zT as functions of their Bi concentration. Additionally, we seek to understand the effect of the lattice contribution to total thermal conductivity for most thermoelectric materials currently being researched. The lattice/total thermal conductivity ratio at the temperature corresponding to the peak zT shows weak material dependence, widely ranging from 0.5 to 0.75, which implies that the lattice thermal conductivity of most thermoelectric materials can be decreased further to improve thermoelectric performance. On the other hand, thermoelectric materials with relatively low ratios exhibit high power factors in their operating temperature ranges, which is ascribed to their excellent electrical performance. These observations provide guidelines to tune transport properties for future applications in thermoelectric power generation.
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