4.6 Article

Facile two step synthesis of chemiresistive sensor based on γFe2O3-activated carbon composites for room temperature alcohol vapour detection

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SPRINGER HEIDELBERG
DOI: 10.1007/s00339-022-05311-8

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Activated carbon; Graphene oxide; Alcohol sensing; Resistivity sensor; Chemiresistor; p-n heterojunction

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In this research, AC-gamma Fe2O3 composite structures were prepared by pyrolysis of bamboo, showing promising alcohol sensing performance at room temperature with fast response, improved range of detection, and sensitivity. The chemiresistive p-n-type heterojunctions formed between AC and gamma Fe2O3 played a crucial role in the material's room temperature alcohol sensing performance.
Here in this research, Activated Carbon (AC)-gamma Fe2O3 composite structures were prepared by pyrolysis of bamboo at 700-1000 degrees C temperatures. Characterization of the as-obtained samples by field-emission scanning electron microscopy, Raman spectroscopy, and X-ray diffraction analysis confirmed the formation of AC-gamma Fe(2)O9(3) composite. The alcohol sensing performance of the composite structure at room temperature was investigated for different ethanol concentrations, which showed self-activated faster response/recovery, improved range of detection, and sensitivity. Ethanol sensing by the drop-carted AC-gamma Fe2O3 films on a glass substrate was tested for various ethanol concentrations ranging from 50 to 500 ppm in water. The chemiresistive p-n-type heterojunctions formed between AC and gamma Fe2O3 were attributed to the room temperature alcohol sensing performance of the material. AC-gamma Fe2O3 prepared at 700 degrees C showed better sensitivity of 49% for 500 ppm ethanol concentration. The quickest response time was found to be 26 s for 100 ppm ethanol concentration with a recovery time of 15 s. [GRAPHICS] .

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