4.7 Article

A novel gasification exfoliation method of the preparation of anhydrous montmorillonite nanosheets for inhibiting restack problem suffering from dehydration

期刊

APPLIED CLAY SCIENCE
卷 217, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.clay.2021.106394

关键词

Montmorillonite; Gasification exfoliation; Liquid nitrogen; Nanosheet

资金

  1. National Natural Science Foundation of China [51904215, 51874220]
  2. Fundamental Research Funds for the Central Universities [WUT: 2020IVB016, 2021-zy-028]
  3. Hubei Key Laboratory of Mineral Resources Processing and Environment (Wuhan University of Technology) [ZHJJ202008]
  4. China Scholarship Council (CSC) -Imperial Scholarship (CSC) [202106950021]

向作者/读者索取更多资源

Anhydrous montmorillonite nanosheets with few layers were successfully prepared through a gasification exfoliation method, addressing the restacking issue of nanosheets. The morphology, structure, and stability characteristics of the anhydrous nanosheets were investigated, showing improved properties compared to those prepared by other methods. The penetration of liquid nitrogen into the interlayer domain of montmorillonite and subsequent gasification played a crucial role in the preparation process.
The exfoliation of montmorillonite (Mt) into nanosheets with mono or few-layer is significant for controllable preparation of Mt. functional nanocomposites, whereas Mt. nanosheets (MtNS) prepared in aqueous solutions usually encountered restack problems suffering from dehydration. In this work, anhydrous MtNS with few layers were successfully prepared through a novel gasification exfoliation method. The quality of morphology, struc-tural and stability characteristics of MtNS were investigated by an atomic force microscope, scanning electron microscope, BET and turbidity. The anhydrous MtNS with a thickness of 0-5 nm were prepared by the liquid nitrogen (LN2) gasification exfoliation. In addition, MtNS prepared through gasification exfoliation presented a looser interlayer structure, higher BET specific surface area and better dispersion stability than those prepared by ultrasonic exfoliation and freeze drying. Thus, the gasification exfoliation perfectly addressed the obstacle of nanosheet restacking. Moreover, molecular dynamics simulation found the LN2 could enter the interlayer domain of Mt. When heating under 70 degrees C, the drastic gasification of LN2 destroyed the weak interlayer binding force of Mt., leading to the successful preparation of anhydrous few-layered MtNS. These findings are expected to provide theoretical guidance for the scalable application of MtNS as functional materials.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据