Rational design of core-shell-structured CoPx@FeOOH for efficient seawater electrolysis

Hydrogen generation by seawater electrolysis is a sustainable approach to renewable-energy conversion which requires efficient catalyst to address challenges such as competing chlorine evolution reaction, chloride corrosion, and catalyst poisoning. Here, core-shell-structured CoPx@FeOOH is designed for selective OER in seawater. This catalyst has high conductivity, large surface area, improved turnover frequency, and optimal absorption energy to OER intermediates, which together lead to excellent catalytic activity. The enhanced chemical stability and corrosion resistance ensure its catalytic performance in seawater. Specifically, it requires overpotentials of 283 and 337 mV to attain current densities of 100 and 500 mA cm-2, respectively, in 1 M KOH seawater, with durability over 80 h of continuous testing without producing any hypochlorite. The CoPx||CoPx@FeOOH pair requires voltages of 1.710 and 1.867 V to attain current densities of 100 and 500 mA cm-2 with a high Faradaic efficiency, showing its great promise for fuel-gas production from seawater.

Automated summary

The core-shell-structured CoPx@FeOOH catalyst designed for seawater electrolysis for hydrogen generation demonstrates excellent catalytic activity, high conductivity, large surface area, improved turnover frequency, optimal absorption energy to OER intermediates, enhanced chemical stability, and corrosion resistance. The CoPx||CoPx@FeOOH pair also shows great promise for fuel-gas production from seawater, with high Faradaic efficiency and low overpotentials required for certain current densities.