Oxygen vacancies in actiniae-like Nb2O5/Nb2C MXene heterojunction boosting visible light photocatalytic NO removal

Photocatalytic oxidation is a green and energy-saving technology for removing the low concentration NO in ambient atmosphere. High efficient and stable photocatalysts are essential for achieving excellent NO conversion effect. In this work, oxygen vacancy-rich Nb2O5/Nb2C heterojunction photocatalysts were prepared from Nb2C MXene by hydrothermal process and heat treatment in H-2/Ar. The (001) facet-dominant Nb2O5 nanorods in-situ grown on Nb2C MXene formed an actiniae-like structure, which promotes the active site exposure and enlarges the reaction interface. Under visible light, the optimized photocatalyst exhibits excellent NO removal rates in the relative humidity range of 25-75%. Mechanism research shows that the oxygen vacancies greatly improve the photocatalytic NO oxidation capacity. Oxygen vacancies on (001) facet of Nb2O5 nanorods can boost the visible light absorption, effectively adsorb and activate the reactant gas. The separation of photogenerated carriers was synergistically enhanced by the oxygen vacancies and Nb2O5/Nb2C heterojunction.

Automated summary

The study demonstrated the excellent NO removal rates under visible light in the relative humidity range of 25-75% by preparing oxygen vacancy-rich Nb2O5/Nb2C heterojunction photocatalysts; the presence of oxygen vacancies greatly enhances the photocatalytic oxidation capacity of nitrogen oxides.