4.6 Article

Heterogenization of Pd(II) complexes as catalysts for the Suzuki-Miyaura reaction

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From the grafting of NHC-based Pd(II) complexes onto TiO2 to the in situ generation of Mott-Schottky heterojunctions: The boosting effect in the Suzuki-Miyaura reaction. Do the evolved Pd NPs act as reservoirs?

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Summary: The study on a series of palladium(II) complexes with bis(NHC) ligands immobilized on TiO2 surface reveals that these complexes evolve to Pd NPs at the TiO2 surface under reaction conditions, releasing Pd species in the liquid phase. The reactivity is enhanced by the in situ generation of Mott-Schottky heterojunctions, leading to new pathways for the design of heterogenized catalysts in reverse-flow reactors.

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