期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 61, 期 13, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202117101
关键词
Covalent Organic Frameworks; Functionalization; Hydrogen Adsorption; Porous Organic Materials
资金
- National Natural Science Foundation of China [22025504, 21621001, 22105082, 21390394]
- 111 project [BP0719036, B17020]
- China Postdoctoral Science Foundation [2020TQ0118, 2020M681034]
- program for JLU Science and Technology Innovative Research Team
In this study, two non-interpenetrated three-dimensional COFs, named JUC-596 and JUC-597, were successfully reported by using the combination of tetrahedral and triangular prism building units. JUC-596 exhibited exceptional performance in H-2 adsorption, surpassing previous benchmarks from porous organic materials. The strong interaction between H-2 and COF materials was verified through theoretical calculations.
Owing to the finite building blocks and difficulty in structural identification, it remains a tremendous challenge to elaborately design and synthesize three-dimensional covalent organic frameworks (3D COFs) with predetermined topologies. Herein, we report the first two cases of 3D COFs with the non-interpenetrated hea net, termed JUC-596 and JUC-597, by using the combination of tetrahedral and triangular prism building units. Due to the presence of triptycene functional groups and fluorine atoms, JUC-596 exhibits an exceptional performance in the H-2 adsorption up to 305 cm(3) g(-1) (or 2.72 wt%) at 77 K and 1 bar, which is higher than previous benchmarks from porous organic materials reported so far. Furthermore, the strong interaction between H-2 and COF materials is verified through the DFT theoretical calculations. This work represents a captivating example of rational design of functional COFs based on a reticular chemistry guide and demonstrates its promising application in clean energy storage.
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