Spin Crossover in a Cobalt Complex on Ag(111)

Review Chemistry, Multidisciplinary

Sublimable Spin-Crossover Complexes: From Spin-State Switching to Molecular Devices

Kuppusamy Senthil Kumar et al.

Summary: This review covers the advances in vacuum-sublimable SCO complexes, including the design and synthesis of functional SCO complexes, on-surface SCO of thin films, and various device architectures based on sublimable SCO complexes.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Chemistry, Multidisciplinary

Spin-Crossover Molecules on Surfaces: From Isolated Molecules to Ultrathin Films

Lalminthang Kipgen et al.

Summary: This article summarizes the research on spin-crossover molecules on solid surfaces in molecular spintronics, covering a range from single molecules to ultrathin films, mainly in the sub-10 nm range. The achievements, challenges, and prospects in this field are highlighted.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Electron-Induced Spin-Crossover in Self-Assembled Tetramers

Sven Johannsen et al.

Summary: The behavior of spin crossover compound on a silver surface was investigated, revealing that two molecules in tetramers can switch states by current injection with significantly higher yields compared to other systems. The other two molecules remain unchanged, but can be used as contacts for switching neighboring molecules. A model of tetramer structure was proposed and validated through experiments.

ACS NANO (2021)

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Article Chemistry, Physical

Thermal- and Light-Induced Spin-Crossover Characteristics of a Functional Iron(II) Complex at Submonolayer Coverage on HOPG

Sangeeta Thakur et al.

Summary: The study focuses on the role of molecule-substrate interactions in the spin-state switching characteristics of surface-bound thin films of SCO complexes. The submonolayer coverage of the complex exhibits a mixed spin-state, showcasing the impact of molecular interactions on thermal switching. The efficiency of light-induced spin switching suggests potential for light-addressable molecular devices based on SCO complexes.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

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Article Chemistry, Physical

Probing the Spin State of Spin-Crossover Complexes on Surfaces with Vacuum Ultraviolet Angle-Resolved Photoemission Spectroscopy

Sebastian Rohlf et al.

Summary: Spin-crossover complexes in direct contact with substrates have attracted interest for potential applications in molecular electronics. A methodology using vacuum ultraviolet photoemission spectroscopy was detailed to determine the spin state of layers of different spin-crossover complexes in submonolayer regime. The relaxation dynamics of spin-crossover layers and the influence of ultraviolet light on these dynamics were investigated.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

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Article Chemistry, Inorganic & Nuclear

Spin Transition of an Iron(II) Organoborate Complex in Different Polymorphs and in Vacuum-Deposited Thin Films: Influence of Cooperativity

Sascha Ossinger et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Anomalous Light-Induced Spin-State Switching for Iron(II) Spin-Crossover Molecules in Direct Contact with Metal Surfaces

Luqiong Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Iron in a Cage: Fixation of a Fe(II)tpy2Complex by Fourfold Interlinking

Thomas Brandl et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Chemistry, Inorganic & Nuclear

Spin-Crossover Complexes in Direct Contact with Surfaces

Manuel Gruber et al.

MAGNETOCHEMISTRY (2020)

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Article Chemistry, Physical

Fragmentation and Distortion of Terpyridine-Based Spin-Crossover Complexes on Au(111)

Thomas Knaak et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2019)

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Article Chemistry, Physical

Influence of Substrate Electronic Properties on the Integrity and Functionality of an Adsorbed Fe(II) Spin-Crossover Compound

Sebastian Rohlf et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2019)

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Article Chemistry, Physical

Importance of Epitaxial Strain at a Spin-Crossover Molecule-Metal Interface

Cynthia Fourmental et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2019)

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Article Chemistry, Multidisciplinary

Engineering On-Surface Spin Crossover: Spin-State Switching in a Self-Assembled Film of Vacuum-Sublimable Functional Molecule

Kuppusamy Senthil Kumar et al.

ADVANCED MATERIALS (2018)

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Article Multidisciplinary Sciences

Evolution of cooperativity in the spin transition of an iron(II) complex on a graphite surface

Lalminthang Kipgen et al.

NATURE COMMUNICATIONS (2018)

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Review Physics, Condensed Matter

Controlling the magnetism of adsorbed metal-organic molecules

Wolfgang Kuch et al.

JOURNAL OF PHYSICS-CONDENSED MATTER (2017)

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Article Chemistry, Physical

Spin crossover in Fe(phen)2(NCS)2 complexes on metallic surfaces

Manuel Gruber et al.

JOURNAL OF CHEMICAL PHYSICS (2017)

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Article Chemistry, Physical

Vacuum-Evaporable Spin-Crossover Complexes in Direct Contact with a Solid Surface: Bismuth versus Gold

Sascha Ossinger et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2017)

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Article Chemistry, Physical

Deposition of a Cationic FeIII Spin-Crossover Complex on Au(111): Impact of the Counter Ion

Torben Jasper-Toennies et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2017)

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Article Physics, Condensed Matter

Soft-x-ray-induced spin-state switching of an adsorbed Fe(II) spin-crossover complex

Lalminthang Kipgen et al.

JOURNAL OF PHYSICS-CONDENSED MATTER (2017)

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Article Chemistry, Multidisciplinary

Robust and Selective Switching of an FeIII Spin-Crossover Compound on Cu2N/Cu(100) with Memristance Behavior

Torben Jasper-Toennies et al.

NANO LETTERS (2017)

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Article Chemistry, Physical

Exchange Coupling of Spin-Crossover Molecules to Ferromagnetic Co Islands

Saber Gueddida et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2016)

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Article Multidisciplinary Sciences

Molecular-scale dynamics of light-induced spin cross-over in a two-dimensional layer

Kaushik Bairagi et al.

NATURE COMMUNICATIONS (2016)

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Article Chemistry, Multidisciplinary

Highly Efficient Thermal and Light-Induced Spin-State Switching of an Fe(II) Complex in Direct Contact with a Solid Surface

Matthias Bernien et al.

ACS NANO (2015)

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Article Chemistry, Inorganic & Nuclear

Pressure induced separation of phase-transition-triggered-abrupt vs. gradual components of spin crossover

Reece G. Miller et al.

DALTON TRANSACTIONS (2015)

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Article Materials Science, Multidisciplinary

Spin state of spin-crossover complexes: From single molecules to ultrathin films

Manuel Gruber et al.

PHYSICAL REVIEW B (2014)

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Editorial Material Materials Science, Multidisciplinary

Emerging properties and applications of spin crossover nanomaterials

Gabor Molnar et al.

JOURNAL OF MATERIALS CHEMISTRY C (2014)

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Article Chemistry, Multidisciplinary

Iron(II) spin crossover films on Au(111): scanning probe microscopy and photoelectron spectroscopy

Alex Pronschinske et al.

CHEMICAL COMMUNICATIONS (2013)

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Article Chemistry, Multidisciplinary

Spin-Crossover Complex on Au(111): Structural and Electronic Differences Between Mono- and Multilayers

Thiruvancheril G. Gopakumar et al.

CHEMISTRY-A EUROPEAN JOURNAL (2013)

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Article Chemistry, Physical

Temperature- and Light-Induced Spin Crossover Observed by X-ray Spectroscopy on Isolated Fe(II) Complexes on Gold

Ben Warner et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2013)

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Article Chemistry, Multidisciplinary

Electron-Induced Spin Crossover of Single Molecules in a Bilayer on Gold

Thiruvancheril G. Gopakumar et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

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Article Chemistry, Inorganic & Nuclear

Nine non-symmetric pyrazine-pyridine imide-based complexes: reversible redox and isolation of [MII/III(pypzca)2]0/+ when M = Co, Fe

Matthew G. Cowan et al.

DALTON TRANSACTIONS (2012)

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Article Chemistry, Physical

Spin crossover materials evaporated under clean high vacuum and ultra-high vacuum conditions: from thin films to single molecules

Tatiana Palamarciuc et al.

JOURNAL OF MATERIALS CHEMISTRY (2012)

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Article Chemistry, Physical

Spin Crossover in a Vacuum-Deposited Submonolayer of a Molecular Iron(II) Complex

Matthias Bernien et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2012)

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Article Chemistry, Multidisciplinary

Reversible Switching of a Cobalt Complex by Thermal, Pressure, and Electrochemical Stimuli: Abrupt, Complete, Hysteretic Spin Crossover

Matthew G. Cowan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

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Article Multidisciplinary Sciences

Robust spin crossover and memristance across a single molecule

Toshio Miyamachi et al.

NATURE COMMUNICATIONS (2012)

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Article Chemistry, Inorganic & Nuclear

Spin-crossover in cobalt(II) compounds containing terpyridine and its derivatives

Shinya Hayami et al.

COORDINATION CHEMISTRY REVIEWS (2011)

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Spin Crossover in a Cobalt Complex on Ag(111)

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