期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 61, 期 4, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202112097
关键词
high water-stable MOFs; indoor air purification; indoor humidity control; MOF pore-nanospace engineering; water-adsorption based applications
资金
- NSFC [21821003, 21890380, 21720102007, 21701200, 22001271]
- LIRT Project of Guangdong PRTP [2017BT01C161]
- Guang Dong Basic and Applied Basic Research Foundation [2020A1515110365]
- FRF for the Central Universities
The study focuses on developing a pore-nanospace post-engineering strategy to optimize the hydrophilicity, water-uptake capacity and air-purifying ability of metal-organic frameworks (MOFs). A moderately hydrophilic MOF (UiO-67-4Me-NH2-38%) with high thermal, hydrolytic and acid-base stability was identified, showing potential for efficient moisture control and pollutants sequestration in confined indoor environments. Exceptional attributes such as water-uptake working capacity/efficiency, contaminants removal, recyclability and regeneration make it a promising candidate for indoor air quality improvement.
The indoor air quality is of prime importance for human daily life and health, for which the adsorbents like zeolites and silica-gels are widely used for air dehumidification and harmful gases capture. Herein, we develop a pore-nanospace post-engineering strategy to optimize the hydrophilicity, water-uptake capacity and air-purifying ability of metal-organic frameworks (MOFs) with long-term stability, offering an ideal candidate with autonomous multi-functionality of moisture control and pollutants sequestration. Through variant tuning of organic-linkers carrying hydrophobic and hydrophilic groups in the pore-nanospaces of prototypical UiO-67, a moderately hydrophilic MOF (UiO-67-4Me-NH2-38 %) with high thermal, hydrolytic and acid-base stability is screened out, featuring S-shaped water sorption isotherms exactly located in the recommended comfortable and healthy ranges of relative humidity for indoor ventilation (45 %-65 % RH) and adverse health effects minimization (40-60 % RH). Its exceptional attributes of water-uptake working capacity/efficiency, contaminants removal, recyclability and regeneration promise a great potential in confined indoor environment application.
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