期刊
ANALYTICA CHIMICA ACTA
卷 1190, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.aca.2021.339249
关键词
Electrodeposition; Cu-Sn alloy; Nanosheet arrays; Glucose biosensor
资金
- National Natural Science Foundation of China [61971274, 62171268]
In this study, morphology-controlled Cu-Sn alloy nanosheet arrays were fabricated using a facile electrodeposition technique, and they exhibited high specific surface energy and abundant active sites. The Cu-Sn/CP electrode served as a self-supported electrode for efficient nonenzymatic glucose sensing with wide linear ranges, low detection limit, excellent selectivity, and stability.
Nanoalloy shows significant advantages and broad application prospects in chemical catalysis, due to the possessed high specific surface energy and abundant active sites can greatly promote their catalytic performance. In this work, morphology-controlled Cu-Sn alloy nanosheet arrays supported on carbon fiber paper (CP) substrate (Cu-Sn/CP) have been developed by a facile one-step electrodeposition technique at room temperature for the first time. Benefiting from the large active surface area, considerable ion transport channels and strong synergistic catalytic effect between Cu and Sn, the as-prepared Cu-Sn/CP served as a self-supported electrode for efficient nonenzymatic glucose sensing. Under optimized conditions, Cu-Sn/CP electrode offers wide linear ranges of 0.0005-2.0 mM and 2.0-10.0 mM, respectively. The detection limit is as low as 0.061 mu M (S/N = 3). Cu-Sn/CP electrode also exhibited excellent selectivity and stability. Additionally, the proposed sensor is proven to be suitable for the detection of glucose in human serum samples. (C) 2021 Elsevier B.V. All rights reserved.
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