期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 363, 期 23, 页码 5168-5195出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202100746
关键词
heterocycles; annulation; ring-opening; metal-catalyzed; organocatalyzed; metal-free
资金
- National Natural Science Foundation of China [22078192, 31702070]
- Natural Science Foundation of Shanghai [19ZR1437900]
- Shanghai University of Engineering Science [E3-0903-19-01366]
- RUDN University Strategic Academic Leadership Program
Oxazolidinone, as a class of important cyclic carbamates, plays a pivotal role in modern organic synthesis and pharmacology. Recent research has focused on their synthesis and ring-opening transformations, aiming to provide researchers opportunities for discovering new reactions.
Oxazolidinone represents a class of most important five-membered cyclic carbamates. They are of great significance for modern organic synthesis and are widespread as pharmacologically active compounds. This review summarizes recent advances in the chemistry of 2-oxazolidinones, with an emphasis on their synthesis, employing different catalytic systems or catalyst-free conditions, as well as on their ring-opening transformations through decarboxylative coupling, covering the period from 2010 to early 2021. Detailed mechanistic aspects are highlighted, hoping to help researchers to explore the hidden opportunities for reaction discoveries.
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