Enabling Fast Na+ Transfer Kinetics in the Whole-Voltage-Region of Hard-Carbon Anodes for Ultrahigh-Rate Sodium Storage

Article Chemistry, Physical

Self-optimizing weak solvation effects achieving faster low-temperature charge transfer kinetics for high-voltage Na3V2(PO4)2F3 cathode

Liang Deng et al.

Summary: This study constructed a weakly-solvating architecture for the Na3V2(PO4)(2)F-3 cathode, accelerating the kinetics of charge-transfer reactions and improving the capacity retention and energy density of the battery at low temperatures.

ENERGY STORAGE MATERIALS (2022)

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Review Chemistry, Multidisciplinary

Recent Advances and Optimization Strategies on the Electrolytes for Hard Carbon and P-Based Sodium-Ion Batteries

Liying Shen et al.

Summary: This review discusses the potential of hard carbons and P-based materials as promising anodes for sodium ion batteries, emphasizing the importance of electrolyte matching in determining the electrochemical performance of SIBs. Effective optimization strategies involving sodium salts, solvents, and additives are summarized, while challenges and prospects in the field are also addressed.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

MgO-Template Synthesis of Extremely High Capacity Hard Carbon for Na-Ion Battery

Azusa Kamiyama et al.

Summary: High-capacity hard carbon with a reversible capacity of 478 mAh g(-1) is successfully synthesized using MgO-template technique, with nanostructures and synthetic conditions optimized to maximize Na storage properties. Leaching of MgO and carbonization at high temperature result in a large reversible capacity and high Coulombic efficiency of 88% in the first cycle.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

Enabling 6C Fast Charging of Li-Ion Batteries with Graphite/Hard Carbon Hybrid Anodes

Kuan-Hung Chen et al.

Summary: This study demonstrates that by fabricating hybrid anodes with uniform mixtures of graphite and hard carbon, it is possible to achieve high-energy density and efficient fast charging in Li-ion batteries. The optimized hybrid anodes retain significantly higher specific energy after 500 cycles of fast charging compared to graphite anodes under the same conditions, making them a promising solution for electric vehicles.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Physical

Carboxyl-Dominant Oxygen Rich Carbon for Improved Sodium Ion Storage: Synergistic Enhancement of Adsorption and Intercalation Mechanisms

Fei Sun et al.

Summary: In this study, a postengineering method was developed to accurately dope carboxyl groups in a carbon framework, leading to improved Na+ storage properties. Experimental and theoretical analysis showed that the carboxyl groups act as active sites for Na+ adsorption and facilitate diffusion-controlled Na+ insertion, providing new insights for enhancing reversible Na+ storage in carbon materials.

ADVANCED ENERGY MATERIALS (2021)

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Review Chemistry, Physical

Hard Carbon Anodes: Fundamental Understanding and Commercial Perspectives for Na-Ion Batteries beyond Li-Ion and K-Ion Counterparts

Ling-Fei Zhao et al.

Summary: Hard carbon is recognized as a promising anode material for alkali metal-ion batteries, particularly showing outstanding performance in sodium-ion batteries, with in-depth research and commercial prototype demonstration. Challenges and research perspectives for future development and early commercialization of HC-based sodium-ion batteries are also discussed comprehensively.

ADVANCED ENERGY MATERIALS (2021)

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Article Energy & Fuels

Thermally modulated lithium iron phosphate batteries for mass-market electric vehicles

Xiao-Guang Yang et al.

Summary: The development of thermally modulated LFP battery can provide adequate cruise range and extend the range through short recharges, eliminating range anxiety for electric vehicles. Designed to operate at a working temperature of around 60 degrees Celsius in any ambient condition, it promises to be an ideal powertrain for mass-market EVs. Furthermore, utilizing low surface area graphite presents an opportunity to prolong the lifespan of EVs to over two million miles.

NATURE ENERGY (2021)

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Article Chemistry, Physical

Boosting low-temperature sodium/potassium storage performance of Bi via novel electrochemical milling process

B. Wang et al.

Summary: The novel electrochemical milling process (EMP) is used to prepare ultrasmall-sized Bi nanoparticles embedded in a three-dimensional porous carbon framework (EMP-Bi@3DCF), showing excellent sodium/potassium storage performance at -20 degrees C. The ultrafast kinetics process is achieved through the ultrasmall sized Bi nanoparticles via EMP and 3D interconnected porous channels, leading to superior rate performances and long cycle life for both NIBs and KIBs at Low-T.

MATERIALS TODAY ENERGY (2021)

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Article Chemistry, Multidisciplinary

Influence of Pore Architecture and Chemical Structure on the Sodium Storage in Nitrogen-Doped Hard Carbons

Konstantin Schutjajew et al.

Summary: Hard carbon is the preferred material for sodium ion battery anodes, but understanding the sodium storage mechanisms is still incomplete. Research on nitrogen functionalities and pore geometry reveals that nitrogen content affects sloping capacity, while materials with less nitrogen and more extensive graphene layers have higher plateau capacities.

SMALL (2021)

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Article Chemistry, Physical

Probing the Energy Storage Mechanism of Quasi-Metallic Na in Hard Carbon for Sodium-Ion Batteries

Zhaohua Wang et al.

Summary: This study reveals the sodium storage mechanism in hard carbon through theoretical calculations and experimental analysis, particularly focusing on the formation of quasi-metallic sodium and quasi-ionic bond between sodium and carbon. The composition of fully sodiated hard carbon and its corresponding capacity in sodium-ion batteries were estimated, providing important insights into sodium behavior in hard carbon.

ADVANCED ENERGY MATERIALS (2021)

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Article Nanoscience & Nanotechnology

From Micropores to Ultra-micropores inside Hard Carbon: Toward Enhanced Capacity in Room-/Low-Temperature Sodium-Ion Storage

Jinlin Yang et al.

Summary: The pore structure of hard carbon plays a crucial role in the electrochemical properties of sodium-ion batteries. A new molten diffusion-carbonization method was proposed to transform micropores into ultra-micropores, leading to an enhanced capacity and temperature endurance for the carbon anode. The ultra-micropores provide extra Na+ storage sites, contributing to the improved capacity, showing potential for high-performance SIBs.

NANO-MICRO LETTERS (2021)

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Article Chemistry, Physical

Nanometer-size Na cluster formation in micropore of hard carbon as origin of higher-capacity Na-ion battery

Yong Youn et al.

Summary: This study used density functional theory calculations to investigate the origin of high-capacity sodiation in hard carbon, revealing that nanometer-size Na clusters are stable between graphene layers, in addition to adsorption and intercalation mechanisms. The research sheds light on the enhanced capacity mechanism in MgO-templated hard carbon.

NPJ COMPUTATIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Elucidating the Mechanism of Fast Na Storage Kinetics in Ether Electrolytes for Hard Carbon Anodes

Ruiqi Dong et al.

Summary: The sodium storage performance of hard carbon in ether electrolytes is superior, attributed to a unique solvated Na+ and Na+ co-intercalation mechanism in designed monodispersed HC nanospheres. Additionally, a thin solid electrolyte interphase film formed in ether electrolytes facilitates Na+ transportation and results in a high initial Coulombic efficiency.

ADVANCED MATERIALS (2021)

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Review Nanoscience & Nanotechnology

Status and Challenges of Cathode Materials for Room-Temperature Sodium-Sulfur Batteries

Ying Wu et al.

Summary: This review systematically explores the rational design strategies for integrating porous carbon matrix with adsorption-catalysis agents in room-temperature sodium-sulfur batteries, as well as summarizes the multistep reaction mechanism and future prospects for the development of these batteries.

SMALL SCIENCE (2021)

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Review Nanoscience & Nanotechnology

Metal Chalcogenides with Heterostructures for High-Performance Rechargeable Batteries

Yu Li et al.

Summary: Heterostructures have shown significant potential for improving the electrochemical performance of batteries, with metal chalcogenides being a promising material species due to their high theoretical capacity. The concept of constructing heterostructures for electrode materials is considered a promising design approach for next-generation rechargeable batteries.

SMALL SCIENCE (2021)

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Review Nanoscience & Nanotechnology

Recent Advances on Sodium-Ion Batteries and Sodium Dual-Ion Batteries: State-of-the-Art Na+ Host Anode Materials

Decai Gong et al.

Summary: SIBs and SDIBs, as promising alternatives to LIBs, have lower energy density and cycling life due to the large mass and ionic radius of sodium atoms, but recent progress in anode materials offers hope for improving their electrochemical performance.

SMALL SCIENCE (2021)

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Review Nanoscience & Nanotechnology

What Is the Right Carbon for Practical Anode in Alkali Metal Ion Batteries?

Jun Zhang et al.

Summary: Carbon materials play a crucial role in alkali metal ion batteries, where the design of carbon anodes requires consideration of storage, coulombic efficiency, and stability criteria; while the design of carbon frameworks for alloy anodes should follow principles of interface cohesion and structural stability to enhance overall stability and performance.

SMALL SCIENCE (2021)

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Article Nanoscience & Nanotechnology

Developing an Interpenetrated Porous and Ultrasuperior Hard-Carbon Anode via a Promising Molten-Salt Evaporation Method

Zhaohua Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Nanoscience & Nanotechnology

Hyperaccumulation Route to Ca-Rich Hard Carbon Materials with Cation Self-Incorporation and Interlayer Spacing Optimization for High-Performance Sodium-Ion Batteries

Kaihua Yu et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Multidisciplinary

Sodium/Potassium-Ion Batteries: Boosting the Rate Capability and Cycle Life by Combining Morphology, Defect and Structure Engineering

Huijuan Huang et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Physical

Mechanism of Sodium Storage in Hard Carbon: An X-Ray Scattering Analysis

Yusuke Morikawa et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Hard Carbon Nanosheets with Uniform Ultramicropores and Accessible Functional Groups Showing High Realistic Capacity and Superior Rate Performance for Sodium-Ion Storage

Ji-Li Xia et al.

ADVANCED MATERIALS (2020)

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Article Multidisciplinary Sciences

Operando visualisation of battery chemistry in a sodium-ion battery by 23Na magnetic resonance imaging

Joshua M. Bray et al.

NATURE COMMUNICATIONS (2020)

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Article Chemistry, Physical

Revealing the Intercalation Mechanisms of Lithium, Sodium, and Potassium in Hard Carbon

Stevanus Alvin et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Physical

Surface-dominated storage of heteroatoms-doping hard carbon for sodium-ion batteries

Qianzheng Jin et al.

ENERGY STORAGE MATERIALS (2020)

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Article Chemistry, Physical

Toward efficient and high rate sodium-ion storage: A new insight from dopant-defect interplay in textured carbon anode materials

Zengxia Pei et al.

ENERGY STORAGE MATERIALS (2020)

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Article Chemistry, Physical

Elucidating the Sodiation Mechanism in Hard Carbon by Operando Raman Spectroscopy

Julia S. Weaving et al.

ACS APPLIED ENERGY MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Co-Construction of Sulfur Vacancies and Heterojunctions in Tungsten Disulfide to Induce Fast Electronic/Ionic Diffusion Kinetics for Sodium-Ion Batteries

Yu Li et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Electrolyte-Dependent Sodium Ion Transport Behaviors in Hard Carbon Anode

Min Eui Lee et al.

SMALL (2020)

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Article Chemistry, Multidisciplinary

Zinc Oxide Quantum Dots Embedded Porous Carbon Nanosheets for High-Capacity and Ultrastable Lithium-Ion Battery Anodes

Jian Yang et al.

CELL REPORTS PHYSICAL SCIENCE (2020)

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Article Chemistry, Physical

Active sites enriched hard carbon porous nanobelts for stable and high-capacity potassium-ion storage

Kai Zhang et al.

NANO ENERGY (2020)

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Article Chemistry, Multidisciplinary

A revised mechanistic model for sodium insertion in hard carbons

Heather Au et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

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Article Chemistry, Physical

Alkali metal insertion into hard carbon - the full picture

Holger Euchner et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Physical

Solid electrolyte interphase manipulation towards highly stable hard carbon anodes for sodium ion batteries

Panxing Bai et al.

ENERGY STORAGE MATERIALS (2020)

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Article Chemistry, Physical

Superior sodium-storage behavior of flexible anatase TiO2 promoted by oxygen vacancies

Qiao Ni et al.

ENERGY STORAGE MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Self-Supporting, Flexible, Additive-Free, and Scalable Hard Carbon Paper Self-Interwoven by 1D Microbelts: Superb Room/Low-Temperature Sodium Storage and Working Mechanism

Bao-Hua Hou et al.

ADVANCED MATERIALS (2019)

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Article Nanoscience & Nanotechnology

High-Capacity Interstitial Mn-Incorporated MnxFe3-xO4/Graphene Nanocomposite for Sodium-Ion Battery Anodes

Haixia Ren et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Physical

Regulating Pore Structure of Hierarchical Porous Waste Cork-Derived Hard Carbon Anode for Enhanced Na Storage Performance

Yuqi Li et al.

ADVANCED ENERGY MATERIALS (2019)

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Article Chemistry, Physical

Blocks of molybdenum ditelluride: A high rate anode for sodium-ion battery and full cell prototype study

Manas Ranjan Panda et al.

NANO ENERGY (2019)

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Article Chemistry, Physical

Tuning the Closed Pore Structure of Hard Carbons with the Highest Na Storage Capacity

Qingshi Meng et al.

ACS ENERGY LETTERS (2019)

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Article Chemistry, Physical

Electrochemical Properties and Theoretical Capacity for Sodium Storage in Hard Carbon: Insights from First Principles Calculations

Clement Bommier et al.

CHEMISTRY OF MATERIALS (2019)

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Article Materials Science, Multidisciplinary

Hard carbons for sodium-ion batteries: Structure, analysis, sustainability, and electrochemistry

Xinwei Dou et al.

MATERIALS TODAY (2019)

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Article Chemistry, Physical

High Energy Density Sodium-Ion Battery with Industrially Feasible and Air-Stable O3-Type Layered Oxide Cathode

Jianqiu Deng et al.

ADVANCED ENERGY MATERIALS (2018)

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Article Chemistry, Multidisciplinary

Rational Design and General Synthesis of S-Doped Hard Carbon with Tunable Doping Sites toward Excellent Na-Ion Storage Performance

Zhensheng Hong et al.

ADVANCED MATERIALS (2018)

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Article Chemistry, Physical

An Ultralong Lifespan and Low-Temperature Workable Sodium-Ion Full Battery for Stationary Energy Storage

Ying-Ying Wang et al.

ADVANCED ENERGY MATERIALS (2018)

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Article Chemistry, Physical

Insights into the Na+ Storage Mechanism of Phosphorus-Functionalized Hard Carbon as Ultrahigh Capacity Anodes

Yu Li et al.

ADVANCED ENERGY MATERIALS (2018)

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Article Chemistry, Physical

Elucidation of the Sodium-Storage Mechanism in Hard Carbons

Panxing Bai et al.

ADVANCED ENERGY MATERIALS (2018)

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Article Chemistry, Physical

Target construction of ultrathin graphitic carbon encapsulated FeS hierarchical microspheres featuring superior low-temperature lithium/sodium storage properties

Hong-Hong Fan et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

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Article Chemistry, Physical

Expanded biomass-derived hard carbon with ultrastable performance in sodium-ion batteries

Ziyi Zhu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

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Article Chemistry, Physical

Insights on the Na+ ion storage mechanism in hard carbon: Discrimination between the porosity, surface functional groups and defects

Camelia Matei Ghimbeu et al.

NANO ENERGY (2018)

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Article Chemistry, Multidisciplinary

Exploring Sodium-Ion Storage Mechanism in Hard Carbons with Different Microstructure Prepared by Ball-Milling Method

Haiyan Lu et al.

SMALL (2018)

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Article Chemistry, Physical

Pre-Oxidation-Tuned Microstructures of Carbon Anodes Derived from Pitch for Enhancing Na Storage Performance

Yaxiang Lu et al.

ADVANCED ENERGY MATERIALS (2018)

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Article Chemistry, Physical

Facile synthesis ofN,O-codoped hard carbon on the kilogram scale for fast capacitive sodium storage

Man Huang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

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Article Chemistry, Multidisciplinary

S-Doped N-Rich Carbon Nanosheets with Expanded Interlayer Distance as Anode Materials for Sodium-Ion Batteries

Jiqian Yang et al.

ADVANCED MATERIALS (2017)

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Article Chemistry, Physical

Manipulating Adsorption-Insertion Mechanisms in Nanostructured Carbon Materials for High-Efficiency Sodium Ion Storage

Shen Qiu et al.

ADVANCED ENERGY MATERIALS (2017)

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Article Chemistry, Physical

Capacitance-enhanced sodium-ion storage in nitrogen-rich hard carbon

Rohit Ranganathan Gaddam et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

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Article Nanoscience & Nanotechnology

Coupled Carbonization Strategy toward Advanced Hard Carbon for High-Energy Sodium-Ion Battery

Huimin Zhang et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

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Article Chemistry, Multidisciplinary

MoSe2-Covered N,P-Doped Carbon Nanosheets as a Long-Life and High-Rate Anode Material for Sodium-Ion Batteries

Feier Niu et al.

ADVANCED FUNCTIONAL MATERIALS (2017)

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Article Chemistry, Physical

Correlation Between Microstructure and Na Storage Behavior in Hard Carbon

Biao Zhang et al.

ADVANCED ENERGY MATERIALS (2016)

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Article Chemistry, Multidisciplinary

Mechanistic insights into sodium storage in hard carbon anodes using local structure probes

Joshua M. Stratford et al.

CHEMICAL COMMUNICATIONS (2016)

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Article Chemistry, Physical

Hard Carbon Microtubes Made from Renewable Cotton as High-Performance Anode Material for Sodium-Ion Batteries

Yunming Li et al.

ADVANCED ENERGY MATERIALS (2016)

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Article Chemistry, Multidisciplinary

Large-scale highly ordered Sb nanorod array anodes with high capacity and rate capability for sodium-ion batteries

Liying Liang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2015)

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Article Chemistry, Multidisciplinary

New Mechanistic Insights on Na-Ion Storage in Nongraphitizable Carbon

Clement Bommier et al.

NANO LETTERS (2015)

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Article Chemistry, Physical

In situ Raman study of lithium-ion intercalation into microcrystalline graphite

Christopher Sole et al.

FARADAY DISCUSSIONS (2014)

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Article Multidisciplinary Sciences

Expanded graphite as superior anode for sodium-ion batteries

Yang Wen et al.

NATURE COMMUNICATIONS (2014)

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Article Chemistry, Multidisciplinary

Manifestation of Charged and Strained Graphene Layers in the Raman Response of Graphite Intercalation Compounds

Julio C. Chacon-Torres et al.

ACS NANO (2013)

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Article Chemistry, Multidisciplinary

Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications

Yuliang Cao et al.

NANO LETTERS (2012)

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Article Chemistry, Multidisciplinary

Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries

Shinichi Komaba et al.

ADVANCED FUNCTIONAL MATERIALS (2011)

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Article Geochemistry & Geophysics

Determination of the aromaticity and the degree of aromatic condensation of a thermosequence of wood charcoal using NMR

Anna V. McBeath et al.

ORGANIC GEOCHEMISTRY (2011)

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Article Chemistry, Multidisciplinary

Pyrolytic carbons from acid/base-treated rice husk as lithium-insertion anode materials

George Ting-Kuo Fey et al.

PURE AND APPLIED CHEMISTRY (2010)

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Article Geochemistry & Geophysics

Variation in the degree of aromatic condensation of chars

Anna V. McBeath et al.

ORGANIC GEOCHEMISTRY (2009)

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Article Electrochemistry

High capacity anode materials for rechargeable sodium-ion batteries

DA Stevens et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2000)

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Enabling Fast Na+ Transfer Kinetics in the Whole-Voltage-Region of Hard-Carbon Anodes for Ultrahigh-Rate Sodium Storage

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