4.8 Review

Nickel-Based Materials for Advanced Rechargeable Batteries

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Bimetallic SnS2/NiS2@S-rGO nanocomposite with hierarchical flower-like architecture for superior high rate and ultra-stable half/full sodium-ion batteries

Huan Li et al.

Summary: The novel material SnS2/NiS2@S-rGO shows promising performance in sodium-ion batteries, exhibiting excellent rate capability and cycling stability. The synergy effect of NiS2 and SnS2 enhances the electrochemical performance, while the S-rGO network improves conductivity and ion transfer rate.

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Article Materials Science, Multidisciplinary

A nanostructured Ni/T-Nb2O5@carbon nanofibers as a long-life anode material for lithium-ion batteries

Si-Ru He et al.

Summary: In this study, nickel/T-Nb2O5 nanoparticles encapsulated in mesoporous carbon nanofibers (Ni/T-Nb2O5@CNFs) were prepared, showing high surface area and mesoporous microstructure. The nanocomposite exhibited excellent capacity and rate performance, making it a promising candidate for anode material in high-power LIBs.

RARE METALS (2021)

Review Chemistry, Physical

Host Materials Anchoring Polysulfides in Li-S Batteries Reviewed

Lei Zhou et al.

Summary: Lithium-sulfur batteries are seen as a viable alternative to future energy storage devices due to their high theoretical energy density. However, the main challenge lies in the leakage and migration of sulfur species. Recent research has focused on developing sulfur host materials that can effectively anchor polysulfides for improved battery performance.

ADVANCED ENERGY MATERIALS (2021)

Article Materials Science, Multidisciplinary

Suppressing capacity fading and voltage decay of Ni-rich cathode material by dual-ion doping for lithium-ion batteries

Hao Liu et al.

Summary: In this study, a novel strategy was proposed to modify the Ni-rich cathode LiNi(0.8)Co(0.1)Mn(0.1)O(2) with uniform Al and Ti cations co-doping, which effectively stabilized the vulnerable structure and mitigated voltage/capacity attenuation. The modified cathode showed significantly enhanced electrochemical performance, with improved discharge capacity and voltage retention after 200 cycles, even at elevated voltages.

JOURNAL OF MATERIALS SCIENCE (2021)

Article Chemistry, Physical

Bulk fatigue induced by surface reconstruction in layered Ni-rich cathodes for Li-ion batteries

Chao Xu et al.

Summary: A structure-driven degradation mechanism is proposed for Ni-rich layered cathode material NMC811, in which a proportion of the material exhibits a lowered accessible state of charge and becomes fatigued after repetitive cycling. This degradation is attributed to high interfacial lattice strain between the reconstructed surface and the bulk layered structure above a distinct threshold.

NATURE MATERIALS (2021)

Article Chemistry, Physical

Hierarchical modulation of NiSe2 nanosheets/nanodendrites by phase engineering on N-doped 3D porous graphene as self-supporting anode for superior lithium ion batteries

Chencheng Zhou et al.

Summary: In order to tackle the issues of fossil fuel shortage and environmental pollution, lithium-ion batteries (LIBs) have been extensively researched as a sustainable green energy source. The hierarchical NiSe2@NPG structure shows promising specific capacities at various current densities, making it a potential candidate for lithium-ion battery anode material.

APPLIED SURFACE SCIENCE (2021)

Article Electrochemistry

Enhanced interfacial reaction interface stability of Ni-rich cathode materials by fabricating dual-modified layer coating for lithium-ion batteries

Hongqiang Wang et al.

Summary: This study presents a coating modification strategy to synthesize LiAlO2/LiF&AlF3 hybrid coating layer on the surface of LiNi0.6Co0.2Mn0.2O2 materials, which effectively mitigates structural degradation and intergranular cracks, demonstrating good performance during long-term cycling.

ELECTROCHIMICA ACTA (2021)

Article Materials Science, Multidisciplinary

Fabrication of Ni3S2 nanoneedle-sheets electrode material with ultrahigh areal capacity of over 15 mAh cm-2

Wenhe Xie et al.

Summary: Large scale Ni3S2 nanoneedle-sheets array was successfully fabricated via facile hydrothermal method, demonstrating extraordinary reversible areal capacity when applied as electrode for Lithium-ion batteries.

MATERIALS LETTERS (2021)

Article Chemistry, Physical

Nano-size NiS particles anchored on nitrogen-doped reduced graphene oxide for superior sodium storage

Shunjiang Zhang et al.

Summary: A hybrid composite, NiS@N-rGO, consisting of nickel sulfide nanoparticles anchored on nitrogen-doped reduced graphene oxide, exhibits high electronic conductivity and accelerated ion diffusion, showing excellent performance as an anode material in sodium-ion batteries.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Chemistry, Physical

A highly stable cathode for lithium-sulfur battery built of Ni-doped carbon framework linked to CNT

Donghua Wang et al.

Summary: A MOF-doping strategy was developed to construct a hollow porous carbon framework (Ni/Co-CNT/NHPC) for lithium-sulfur batteries, which significantly improved the cycling stability and rate capability.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Energy & Fuels

A Low Temperature Self-Assembled ZrO2 Layer as a Surface Modification for High Energy Density Ni-Rich Cathode Materials in a Lithium-Ion Battery

Van-Chuong Ho et al.

Summary: Research shows that surface coating of Ni-rich layered oxide cathodes can improve electrochemical performance, with the self-assembled ZrO2 coating enhancing surface stability and promoting high lithium ion diffusion.

ENERGY TECHNOLOGY (2021)

Article Chemistry, Physical

Boosting the lithium storage performance by synergistically coupling ultrafine heazlewoodite nanoparticle with N, S co-doped carbon

Jiabao Li et al.

Summary: Transition metal sulfides have shown potential as high-performance electrode candidates for lithium-ion batteries due to their high activity towards lithium storage and diverse structures. A unique hybrid structure with ultrafine heazlewoodite nanoparticles in-situ confined in nitrogen and sulfur dual-doped carbon was constructed, resulting in enhanced structure stability, shortened Li+ migration distance, and improved reaction dynamics for high lithium storage performance. The fundamental understanding of the improved lithium storage of this structure revealed the synergistic coupling between Ni3S2 and NSC at the hetero-interface through doped sulfur atoms.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Article Chemistry, Physical

Highly Stable Spinel Oxide Cathode for Rechargeable Li-O2 Batteries in Non-Aqueous Liquid and Gel-Based Electrolytes

Keerti M. Naik

Summary: Metal-air batteries, particularly lithium-oxygen batteries, are promising for high energy density applications. A low-cost bimetallic spinet oxide NiFe2O4 electrocatalyst was synthesized and found to enhance the performance of Li-O-2 batteries by improving discharge capacity, cyclic stability, and reducing overpotential.

ACS APPLIED ENERGY MATERIALS (2021)

Article Nanoscience & Nanotechnology

Yttrium Surface Gradient Doping for Enhancing Structure and Thermal Stability of High-Ni Layered Oxide as Cathode for Li-Ion Batteries

Yang-Yang Wang et al.

Summary: The authors improved the structure and thermal stability of high-nickel layered oxides by introducing yttrium through surface gradient doping, leading to enhanced electrochemical performance. The yttrium-doped sample showed good capacity retention, potential stability, and superior thermal behavior, attributed to strong yttrium-oxygen bonding and a stable oxygen framework on the surface layer.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Engineering, Environmental

Highly conductive 3D structural carbon network-encapsulated Ni-rich LiNi0.8Co0.1Mn0.1O2 as depolarized and passivated cathode for lithium-ion batteries

Jeonguk Hwang et al.

Summary: In this study, a highly conductive and ethanol-dispersive 3D carbon network was successfully applied to improve the electrochemical performance of Ni-rich NCM, enhancing depolarization and achieving stable electrochemical reactions at high rates. The 3D carbon network layer also prevented electrical separation caused by micro-cracks, irreversible phase transitions, and side reactions with electrolytes, leading to a significant improvement in rate capability and cycle stability compared to bare NCM811.

CHEMICAL ENGINEERING JOURNAL (2021)

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Gas-phase construction of holey exfoliated graphite supported NiS nanoparticles with superior electrochemical performance for sodium-ion batteries

Lina Wang et al.

Summary: By utilizing exfoliated graphite with holey structure as a matrix material, along with a gas-phase strategy to disperse NiS nanoparticles, the NiS/HEG electrode displays enhanced rate performance and cycling stability, showcasing improved charge transfer efficiency and ion diffusion kinetics.

MATERIALS LETTERS (2021)

Article Electrochemistry

NiS2 wrapped into graphene with strong Ni-O interaction for advanced sodium and potassium ion batteries

Wei Li et al.

Summary: Sodium/potassium ion batteries have attracted attention for their low cost and energy density similar to lithium-ion batteries. Graphene-supported NiS2 nanocrystals with a strong Ni-O interaction were used as universal anode materials, showing high cycle stability and reversible capacity in both SIB and PIB. The study sheds light on manipulating nickel-sulfide/rGO based materials through interfacial engineering for high-performance energy storage devices.

ELECTROCHIMICA ACTA (2021)

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Flower-like Ni3S2 hollow microspheres as superior sulfur hosts for lithium-sulfur batteries

Yajing Yan et al.

Summary: Lithium sulfur batteries are promising for energy storage, but the low utilization efficiency of sulfur and shuttle effect of polysulfides hinder their development. This study utilized porous Ni3S2 hollow microspheres as sulfur hosts, improving cycling performance and rate capability. The research offers a simple route for developing transition metal sulfides with hollow structures as superior sulfur hosts for Li-S batteries.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

Article Chemistry, Physical

Improved electrochemical performance of LiMn1.5M0.5O4 (M=Ni, Co, Cu) based cathodes for lithium-ion batteries

Renato Goncalves et al.

Summary: LiMn2O4 and LiMn1.5M0.5O4 (M: Ni, Cu, Co) doped particles were synthesized by sol-gel, resulting in improved cycling behavior and thermal stability. Doping elements reduced pore size and enhanced thermal stability of LiMn2O4. Different active materials for cathodes showed varied electrochemical performances, with Ni, Cu, and Co doped LiMn2O4 demonstrating improved performance.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Chemistry, Physical

Ni(OH)2 cathode with oxygen vacancies induced from electroxidizing Ni3S2 nanosheets for aqueous rechargeable Ni-Zn battery

Xue Wang et al.

Summary: An efficient electroxidizing approach was proposed to produce Ni3S2/O-v-Ni(OH)(2) electrode, which enhances electron transport rate and exposed active sites, demonstrating remarkable energy density and cycling stability, outperforming most of the recently reported Zn-ion batteries.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Chemistry, Physical

SnO2/NiFe2O4/graphene nanocomposites as anode materials for lithium ion batteries

Honglong Shen et al.

Summary: SnO2/NiFe2O4/graphene (SNG) nanocomposites were synthesized via a one-step hydrothermal method for use in Lithium ion batteries, exhibiting good electrochemical performance. Increasing SnO2 content led to enhanced electrochemical performance, with high reversible and discharge capacities observed. The synergistic effects between NiFe2O4/SnO2 and the SnO2 buffer layers, along with the electrical conductivity enhancement and volume accommodation provided by graphene sheets, contribute to the improved cycling stability and rate capability.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Chemistry, Physical

Bimetallic nickel cobalt sulfides with hierarchical coralliform architecture for ultrafast and stable Na-ion storage

Yanyan He et al.

Summary: A series of bimetallic nickel cobalt sulfides with hierarchical micro/nano architectures were successfully fabricated using a facile synthesis strategy, displaying excellent performance in sodium-ion storage. The enhanced conductivity by bimetallic components, the unique coral-like micro/nanostructure, and fast sodium ion diffusion were key factors contributing to the remarkable electrochemical properties observed during charging and discharging cycles.

NANO RESEARCH (2021)

Article Chemistry, Multidisciplinary

Ni (II) Coordination Supramolecular Grids for Aqueous Nickel-Zinc Battery Cathodes

Xiyue Zhang et al.

Summary: This study reports nickel-ligand coordination grids (NCGs) with a high theoretical capacity that provide fast faradic reactions while maintaining good reversibility. Graphene nanosheet (GN) modification of NCGs substantially boosts surface charge and reduces the work function of supramolecular compounds.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

A Low-Strain Potassium-Rich Prussian Blue Analogue Cathode for High Power Potassium-Ion Batteries

Lin Li et al.

Summary: This study introduces a low-strain potassium-rich cathode material KNiHCF for potassium ion batteries, which exhibits superior discharge capacity and cycling stability due to its low-strain de-/intercalation mechanism, intrinsic semiconductor property, and low potassium diffusion energy barrier.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Materials Science, Ceramics

A biomass-derived biochar-supported NiS/C anode material for lithium-ion batteries

Guanghui Xia et al.

Summary: Researchers have successfully anchored nickel sulfides/carbon composite materials on chestnut shell fluff (CSF)-derived biochar using a glucose-auxiliary hydrothermal method and annealing treatment, resulting in improved battery performance. This study provides new insights for the development of high-performance nickel-based sulfide anode materials for lithium-ion batteries.

CERAMICS INTERNATIONAL (2021)

Article Engineering, Environmental

High performance layered LiNi0.8Co0.07Fe0.03Mn0.1O2 cathode materials for Li-ion battery

Guojun Zha et al.

Summary: By partially substituting Co with Fe, a new cathode material (Fe3-NCM871) with significantly enhanced electrochemical performance was developed. This material showed higher initial capacity, rate capacity, and cycle stability compared to the conventional cathode material NCM811. Density functional theory calculations confirmed that the improved performance was due to reduced Ni/Li exchange content and linear Ni2+-O2--Fe3+ superexchange between layers.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Multidisciplinary

Improving Na+ transport kinetics and Na+ storage of hierarchical rhenium-nickel sulfide (ReS2@NiS2) hollow architecture by assembling layered 2D-3D heterostructures

Zelin Cai et al.

Summary: The ReS2@NiS2 heterostructures, with ReS2 nanosheet arrays anchored on the surface of NiS2 hollow nanosphere, exhibit excellent electrochemical performance in sodium-ion batteries, achieving high specific capacity and stable cycle stability.

CHINESE CHEMICAL LETTERS (2021)

Article Energy & Fuels

Demonstration of Biocarbon-Added NiS Porous Nanospheres as a Potential Anode for Lithium-Ion Batteries

Mullaivananathan Vadivazhagan et al.

Summary: Metal sulfides are being explored as potential anode materials for lithium-ion batteries due to their high capacity, strong mechanical properties, and low cost. The NiS/CPC composite demonstrated superior electrochemical performance with high reversible specific capacity, good cycling stability, and high rate capacity, attributed to the presence of coir-pith-derived carbon providing structural support and improved reaction kinetics.

ENERGY & FUELS (2021)

Article Chemistry, Physical

Amorphous Sn-Ni islets with high structural integrity as an anode material for lithium-ion storage

Ryounghee Kim et al.

Summary: This study demonstrates the use of amorphous Sn-Ni islets as an anode material for lithium-ion storage for the first time. The rapid co-electrodeposition method prevents crystallization, resulting in an alloy with suppressed capacity degradation and potential for use in lithium-ion rechargeable batteries.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Chemistry, Physical

Ultrafine Ni nanoparticles anchored on carbon nanofibers as highly efficient bifunctional air electrodes for flexible solid-state zinc-air batteries

Guoqiang Liu et al.

Summary: The study presents a facile adsorption-pyrolyzation strategy for preparing ultrafine Ni nanoparticles anchored on carbon nanofiber, exhibiting excellent oxygen electrocatalytic activity for flexible all solid-state Zn-air battery applications.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Article Chemistry, Multidisciplinary

Multishelled Ni2P Microspheres as Multifunctional Sulfur Host 3D-Printed Cathode Materials Ensuring High Areal Capacity of Lithium-Sulfur Batteries

Fan Zhang et al.

Summary: This study presents multifunctional Ni2P hollow microspheres as sulfur host materials to overcome the shuttle effect caused by electrolyte-soluble polysulfides, enhancing the discharge capacity and cycle stability of lithium-sulfur batteries.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Article Electrochemistry

A Novel Method to Prepare Flexible 3D NiO Nanosheets Electrodes for Alkaline Rechargeable Ni-Zn Batteries

Kai Zhou et al.

Summary: A novel and eco-friendly strategy involving the cycle of Ni2+ hydrolysis and H+ etching process has been demonstrated to synthesize three-dimensional NiO nanosheets array supported on pressed Ni foam electrode. The resulting NiO/PNF electrode shows excellent mechanical flexibility and stability, with a capacity of 5.08 mAh cm(-3), and the assembled NiO/PNF||Zn battery exhibits peak energy and power densities up to 5.2 mW h cm(-3) and 1944.4 mW cm(-3).

CHEMELECTROCHEM (2021)

Article Chemistry, Physical

Ultrathin Nanosheet-Assembled Flowerlike NiSe2 Catalyst Boosts Sulfur Redox Reaction Kinetics for Li-S Batteries

A-Hu Shao et al.

Summary: Efficient catalytic materials are crucial for improving the kinetics of sulfur redox reactions in lithium-sulfur batteries. In this study, ultrathin nanosheet-assembled flowerlike NiSe2 architectures were demonstrated as highly efficient catalysts for sulfur redox reactions. The NiSe2 structures provide sufficient binding sites for anchoring polysulfides and effectively catalyze polysulfide conversion.

ACS APPLIED ENERGY MATERIALS (2021)

Article Nanoscience & Nanotechnology

All-in-One Sulfur Host: Smart Controls of Architecture and Composition for Accelerated Liquid-Solid Redox Conversion in Lithium-Sulfur Batteries

Bin Qin et al.

Summary: The hierarchical MoC@Ni-NCNT arrays act as a multifunctional sulfur host in Li-S batteries, showing improved high-sulfur-loading performance and long lifespan. The design with MoC porous backbone and NCNT shell effectively traps polysulfides and enhances bidirectional sulfur transformation kinetics, leading to high capacity and superior rate performance. This work opens a new avenue for constructing high-performance LSBs with a multifunctional cathode.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Multidisciplinary

Phase Compatible NiFe2O4 Coating Tunes Oxygen Redox in Li-Rich Layered Oxide

Jiming Peng et al.

Summary: A surface-coating strategy using NiFe2O4 was developed to enhance the performance of Li-rich layered oxides in lithium-ion batteries, resulting in improved cycle stability and rate capability. This strategy effectively traps surface lattice oxygen and restrains cation migration, decoupling the surface oxygen redox from cation movement.

ACS NANO (2021)

Article Chemistry, Physical

Vertical growth of nickel sulfide nanosheets on graphene oxide for advanced sodium-ion storage

Yuanyi Luo et al.

Summary: A two-dimensional vertical aligned nickel sulfide nanosheets grown on reduced graphene oxide (rGO) is designed in this study, which enhances the electrolyte/electrode contact and improves rate-performance and cycling stability. The NiS@rGO composite shows good capacity retention and cycling stability in tests, indicating its potential for sodium-ion battery applications.

CARBON (2021)

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Polypyrrole-enveloped Prussian blue nanocubes with multi-metal synergistic adsorption toward lithium polysulfides: high-performance lithium-sulfur batteries

Meng Du et al.

Summary: The study presents a new strategy of combining PBAs with ppy to construct FeCoNi PBA-S-ppy composite material, addressing the issues of polysulfide shuttling and poor electronic conductivity. The FeCoNi PBA exhibits enhanced LiPS absorption ability and cycling performance, attributed to the multi-metal synergistic adsorption towards LiPS, serving as an effective chemical-anchor.

CHEMICAL ENGINEERING JOURNAL (2021)

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Integration of nickel phosphide nanodot-enriched 3D graphene-like carbon with carbon fibers as self-supported sulfur hosts for advanced lithium sulfur batteries

Jiaqin Liu et al.

Summary: A novel hybrid architecture has been designed and demonstrated for lithium-sulfur batteries, showing excellent performance and cycling stability, indicating a promising practical application perspective.

ELECTROCHIMICA ACTA (2021)

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Study on the synthesis of NiCo2O4 as lithium-ion battery anode using spent LiNi0.6Co0.2Mn0.2O2 batteries

Jie Wu et al.

Summary: This paper successfully combined the recycling of spent LiNi0.6Co0.2Mn0.2O2 lithium-ion battery cathode materials with the synthesis of NiCo2O4 anode material. The NiCo2O4 anode material showed excellent rate performance in the rate test, with stable discharge capacities at different current densities and the ability to restore capacity when the current density returned to a lower level.

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Heterogeneous Fe-Ni-P nanosheet arrays as a potential anode for sodium ion batteries

Guohao Chen et al.

Summary: Transition metal phosphates have high theoretical capacity and low cost, but suffer from poor reaction kinetics and volume expansion. Self-supported iron nickel phosphide composite nanosheet arrays have been successfully synthesized to address these issues, demonstrating remarkable sodium storage capability and good cycling stability.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2021)

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Revisiting the role of Zr doping in Ni-rich layered cathodes for lithium-ion batteries

Chul-Ho Jung et al.

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Soft-templated synthesis of core-shell heterostructured Ni3S2@polypyrrole nanotube aerogels as anode materials for high-performance lithium ion batteries

Bo Wang et al.

Summary: The fabrication of core-shell heterostructured Ni3S2@polypyrrole (Ni3S2@PPy) nanotube aerogels showed superior performance as an anode material for lithium-ion batteries, with high reversible capacity, good rate capability, and improved cycling stability. Its low densities, large surface areas, and three-dimensional network features make them attractive for potential energy conversion/storage devices.

NEW JOURNAL OF CHEMISTRY (2021)

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Triple functionalization of carved N-doped carbon nanoboxes with synergistic trimetallic sulphide for high performance lithium-sulphur batteries†

Yen-Ju Wu et al.

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Directly embedded Ni3S2/Co9S8@S-doped carbon nanofiber networks as a free-standing anode for lithium-ion batteries

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Yehonatan Levartovsky et al.

Summary: Doping with Al and Ti significantly enhances the performance of Ni-rich layered oxide cathode material LiNi0.85Co0.1Mn0.05O2, leading to improved capacity retention, reduced particle cracking, and enhanced thermal stability.

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