4.6 Article

Wetting Stability of Supported Graphene in Ambient Environment

期刊

ADVANCED ENGINEERING MATERIALS
卷 24, 期 6, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adem.202101283

关键词

graphene; stability; substrate; wettability

资金

  1. National Key Research and Development Program of China [2019YFA0705400]
  2. National Natural Science Foundation of China [12172176, 52002175]
  3. Natural Science Foundation of Jiangsu Province [BK20211191, BK20212008]
  4. Research Fund of State Key Laboratory of Mechanics and Control of Mechanical Structures [MCMS-I-0421G01, MCMS-I-0421K01]
  5. China Postdoctoral Science Foundation [2018T110494, 2020TQ0146]
  6. Fundamental Research Funds for the Central Universities [NE2020001, NS2021042, NJ2020003, NZ2020001]
  7. Priority Academic Program Development of Jiangsu Higher Education Institutions

向作者/读者索取更多资源

The wetting stability of supported graphene in ambient environment is evaluated and found to be independent of substrate materials, graphene layer numbers, and long-term air exposure. Both experimental results and theoretical calculations suggest that a monolayer graphene coating can alter the water contact angles of various substrates to a converged value around 80-85 degrees. The stable wettability of graphene is important for its practical applications in functional coatings, liquid gated electronic devices, and other areas requiring its exposure to water.
The evaluation of the wetting stability of supported graphene in ambient environment is important for its practical applications. Herein, it is shown by experiments that a monolayer graphene coating can alter the water contact angles of various substrates to a converged value around 80-85 degrees in ambient environment, almost independent of substrate materials, graphene layer numbers as well as long-term air exposure up to 14 months. First-principles calculations and van der Waals modeling indicate that a monolayer graphene is sufficient to alter both short-range and long-range interactions of a water molecule with various substrates to a converged state. The stable wettability of graphene would facilitate its practical applications, ranging from functional coatings, liquid gated electronic devices, and other areas requiring its exposure to water.

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