Chemical quenching of positronium in OMC/SBA-15,OMC@SBA-15 and CuO@SBA-15 catalysts

Owing to highly ordered two-dimensional hexagonal structure, large surface area, variable pore size, high thermal stability and especially the electron delocalization energy determined by its frame structure, SBA-15catalysts have received more and more researchers' attention. By using the structure-directing agent of P123and the silicon source of TEOS, we synthesize ordered mesoporous silica SBA-15. At the same time, ordered mesoporous carbon OMC is succefully synthesized with the template of SBA-15. The small angle X-raydiffraction, high resolution transmission electron microscopy and N2 adsorption-desorption measurements areconducted to verify the highly ordered pore structure and relatively high specific surface area of SBA-15 andOMC, and their average pore radius are about 7.5 nm and 3.3 nm, respectively. Positron lifetime spectrum ofSBA-15 catalyst is composed of two longer lifetimes and two shorter lifetimes: two longer lifetimes and are the annihilation in micropore and large pore of positronium (Ps), are 7.5 ns and 106 ns. However, there isnearly no longer lifetime component in OMC, which indicates that there might exist the quenching or inhibitingof positronium by carbon material. To verify this guess, we synthesize the catalysts of OMC/SBA-15,OMC@SBA-15 and CuO@SBA-15 by the solid state reaction and the impregnation filling method. With theincreasing of OMC and CuO content, both the o-Ps lifetime and its intensity of these three compounds decrease. The annihilation rate of o-Ps lifetime varying with OMC and CuO content can be better fitted by one or two straight lines, The values of reaction rate constant K in OMC/SBA-15, OMC@SBA-15 and CuO@SBA-15are /, , and respectively. Therefore, our results indicate that there are quenching effect and inhibition effect among the carbon, the CuO and the positronium, which lead and to decrease, and positronium is also a probe for detecting the pore structure of porous material

Automated summary

Due to its unique two-dimensional hexagonal structure, large surface area, and high thermal stability, SBA-15 catalyst has attracted extensive attention. We successfully synthesized ordered mesoporous silica SBA-15 and ordered mesoporous carbon OMC, and verified their highly ordered pore structure and relatively high specific surface area through various testing methods. Furthermore, we discovered the quenching effect and inhibition effect between carbon, CuO, and positronium.