期刊
ACS APPLIED MATERIALS & INTERFACES
卷 14, 期 6, 页码 8025-8035出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c23583
关键词
Be-free KBBF; nontoxic KBBF; ZnNiBO3(OH); cycle stability; high-energy density
资金
- Hong Kong Research Grants Council [CityU 11218420]
- Swedish Research Council [VR-2016-06014, VR-202004410]
This study investigates a new electrode material, ZNBH, which has a reinforced structure and bonding, as well as well-incorporated conductive metals for supercapacitor applications. The enhanced electronic properties of ZNBH are further studied by theoretical calculations. Experimental results show that ZNBH exhibits excellent performance as an electrode material for hybrid supercapacitors.
Not only are new and novel materials sought for electrode material development, but safe and nontoxic materials are also highly being intensively investigated. Herein, we prepare ZnNiBO3(OH) (ZNBH), a modified and Be-free KBe2BO3F2 (KBBF) family member as an effective electrode material. The novel ZNBH resembles the KBBF structure but with reinforced structure and bonding, in addition to well-incorporated conductive metals benefiting supercapacitor applications. The enhanced electronic properties of ZNBH are further studied by means of density functional theory calculations. The as-prepared ZNBH electrode material exhibits a specific capacity of 746 C g(-1) at a current density of 1 A g(-1). A hybrid supercapacitor (HSC) device is fabricated and successfully illuminated multiple color LEDs. Interestingly, even after being subjected to long charge-discharge for 10 000 cycles, the ZNBH//AC HSC device retains 97.2% of its maximum capacity, indicating the practicality of ZNBH as an electrode material.
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