Potentials in Li-Ion Batteries Probed by Operando Ambient Pressure Photoelectron Spectroscopy

The important electrochemical processes in a battery happen at the solid/liquid interfaces. Operando ambient pressure photoelectron spectroscopy (APPES) is one tool to study these processes with chemical specificity. However, accessing this crucial interface and identifying the interface signal are not trivial. Therefore, we present a measurement setup, together with a suggested model, exemplifying how APPES can be used to probe potential differences over the electrode/electrolyte interface, even without direct access to the interface. Both the change in electron electrochemical potential over the solid/liquid interface, and the change in Li chemical potential of the working electrode (WE) surface at Li-ion equilibrium can be probed. Using a Li4Ti5O12 composite as a WE, our results show that the shifts in kinetic energy of the electrolyte measured by APPES can be correlated to the electrochemical reactions occurring at the WE/electrolyte interface. Different shifts in kinetic energy are seen depending on if a phase transition reaction occurs or if a single phase is lithiated. The developed methodology can be used to evaluate charge transfer over the WE/electrolyte interface as well as the lithiation/delithiation mechanism of the WE.

Automated summary

This article presents a method for measuring potential differences at the solid/liquid interface in a battery using operando ambient pressure photoelectron spectroscopy (APPES) and proposes a model. By using a Li4Ti5O12 composite as the working electrode, the study demonstrates that the shifts in kinetic energy measured by APPES can be used to study electrochemical reactions.