4.8 Article

3D V2CTx-rGO Architectures with Optimized Ion Transport Channels toward Fast Lithium-Ion Storage

期刊

ACS APPLIED MATERIALS & INTERFACES
卷 13, 期 51, 页码 61258-61266

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c19596

关键词

V2CTx; MXene; 3D architecture; fast ion transport; lithium-ion storage; XAFS

资金

  1. National Key R&D Program of China [2020YFA0405800, 2017YFA0303500]
  2. NSFC [U1932201, U2032113, 22075264]
  3. CAS Collaborative Innovation Program of Hefei Science Center [2019HSC-CIP002, 2020HSCCIP002]
  4. USTC Research Funds of the Double First-Class Initiative [YD2310002003]
  5. Institute of Energy, Hefei Comprehensive National Science Center, University Synergy Innovation Program of Anhui Province [GXXT-2020-002]
  6. CAS Interdisciplinary Innovation Team, Anhui Provincial Natural Science Foundation [2008085QA28]
  7. Fundamental Research Funds for the Central Universities [WK2310000088]
  8. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education)

向作者/读者索取更多资源

The study interlinks 2D V2CTx MXene nanosheets with rGO to construct a 3D porous V2CTx-rGO composite, which shows improved energy storage performance and stability through close interfacial contact and optimized ion transport channels.
Two-dimensional (2D) MXene materials show great potential in energy storage devices. However, the self-restacking of MXene nanosheets and the sluggish lithium-ion (Li+) kinetics greatly hinder their rate capability and cycling stability. Herein, we interlink 2D V2CTx MXene nanosheets with rGO to construct a 3D porous V2CTx-rGO composite. X-ray spectroscopy study reveals the close interfacial contact between V2CTx and rGO via electron transfer from V to C atoms. Benefiting from the close combination and optimized ion transport channel, V2CTx-rGO offers a high-rate Li+ storage performance and excellent cycling stability over 2000 cycles with negligible capacity attenuation. Moreover, it exhibits a dominant mechanism of intercalation pseudocapacitance and efficient Li+ transport proved by density functional theory calculation. This rationally designed 3D V2CTx-rGO has implications for the study of the MXene composite's structure and energy storage devices with high rate and stability.

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