期刊
ACS APPLIED MATERIALS & INTERFACES
卷 14, 期 4, 页码 5908-5920出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c16723
关键词
palladium; bismuth sulfide; mercury; electrochemical detection; photoreduction
资金
- Ministry of Science and Technology (MOST), Taiwan [MOST-102-2113-M-002-009-MY3, MOST-106-2113-M-027-003-MY3]
A nanocomposite containing palladium nanoparticles embedded on bismuth sulfide nanorods was synthesized and used as an electrochemical sensor for the detection of mercuric ions. The modified electrode showed excellent sensitivity and low detection limit, and also exhibited photocatalytic activity.
A nanocomposite containing palladium nanoparticles embedded on bismuth sulfide nanorods (Pd@Bi2S3) was synthesized based on a solvothermal method. The structural features, composition, and morphology were characterized by XRD, FT-IR, FE-SEM-EDS, FE-TEM, HAADF-STEM, XPS, N-2 physisorption, and UV-vis. Further electrochemical measurements by EIS, CV, DPV, and LSV techniques were done. It revealed that Pd@Bi2S3/GCE were exploited as electrochemical sensors for the detection of toxic mercuric ions (Hg2+), which provides a wide linear range of 0.049-445 mu M, excellent sensitivity of 1.17 mu A mu M-1 cm(-2), and detection limit of 13.5 nM. The modified electrode has also been successfully applied for the detection of Hg2+ in sea fish, river fish, and water samples. The Pd@Bi2S3/GCE signifies a robust, usability, and highly effective method for trace level detection of Hg2+ ions. Furthermore, these Pd@Bi2S3 bifunctional catalysts were discovered to have good photoreduction activity for Hg2+ ions upon the visible-light irradiation.
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