Chromatic Conductive Polymer Nanocomposites of Poly (p-Phenylene Ethynylene)s and Single-Walled Carbon Nanotubes

We report on dispersions and thin films of chromatic conductive nanocomposites of poly(p-phenylene ethynylene)s (PPEs) and single-walled carbon nanotubes (SWNTs) generated via solution mixing. The linear, conjugated PPEs with dialkyl- and dialkyloxy-side chain groups are shown to debundle and disperse high concentration (up to 2.5 mg/mL) SWNTs in various organic solvents. The solubilization of SWNTs and PPE wrapping is accompanied with the change in the solution color. Ultraviolet visible absorption spectra of nanocomposite solutions demonstrate a new absorption peak at a higher wavelength, supporting the observed chromatism. Fluorescence spectra of nanocomposite solutions display significant quenching of the fluorescence intensity and the Stern-Volmer model is used to analyze fluorescence quenching. Electron microscopy of the chromatic solid films of high mass fraction PPE/SWNT nanocomposites obtained by vacuum filtration reveals the debundled SWNTs in the PPE matrix. The tensile strength and Young's modulus of these PPE/SWNT nanocomposite films are as high as 150 MPa and 15 GPa, respectively. The composite films exhibit remarkably high conductivities, ranging from similar to 1000 S/m to similar to 10,000 S/m for 10 wt% and 60 wt% SWNT nanocomposites, respectively.

Automated summary

This study reports the fabrication of chromatic conductive nanocomposites of PPEs and SWNTs via solution mixing, showcasing the dispersing capability of PPEs towards high concentrations of SWNTs in organic solvents. The nanocomposite solutions exhibit new absorption peaks and fluorescence quenching, while the solid films obtained through vacuum filtration display high strength, modulus, and conductivity.