期刊
GREEN CHEMISTRY
卷 18, 期 18, 页码 5015-5024出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6gc00977h
关键词
-
资金
- Laboratory Directed Research and Development Program of Oak Ridge National Laboratory (ORNL)
- BioEnergy Science Center
- Office of Biological and Environmental Research in the DOE Office of Science
- paper science engineering (PSE) fellowship programin Renewable Bioproducts Institute at Georgia Institute of Technology
- U.S. Department of Energy [DE-AC05-00OR22725]
- DOE
Lignins from various poplar genotypes were isolated by using organosolv fractionation and subjected to rheological treatment at various temperatures. Physicochemical characterization of the lignin variants shows a broad distribution of glass transition temperatures, melt viscosity, and pyrolysis char residues. Rheological treatment at 170 degrees C induces lignin repolymerization accompanied with an increase in condensed linkages, molecular weights, and viscosities. In contrast, rheology testing at 190 degrees C results in the decrease in lignin aliphatic and phenolic hydroxyl groups, beta-O-aryl ether linkages, molecular weights, and viscosity values. Lignin under air cooling generates more oxygenated and condensed compounds, but lower amounts of ether linkages than lignin cooled under nitrogen. Lignin with a lower syringyl/guaiacyl ratio tends to form more cross-linkages along with higher viscosity values, higher molecular weight and larger amounts of condensed bonds.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据