期刊
GREEN CHEMISTRY
卷 18, 期 18, 页码 4954-4960出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6gc01229a
关键词
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资金
- Wallonie and European Community
- FEDER program: HYBRITI-MESURF
- MACOBIO
- BIOMAT project
- BIORG-EL project
- INTERREG V program (BIOCOMPAL project)
- Programme d'Excellence FLYCOAT by the Belgian Science Policy Office
- Interuniversity Attraction Poles Program by the Belgian Science Policy Office
A novel benzoxazine monomer containing a carbohydrate moiety was synthesized using a solventless approach from the reaction of arbutin, a naturally occurring phenolic compound, furfurylamine and formaldehyde. The chemical structure of this fully bio-based benzoxazine monomer was confirmed by H-1 NMR and FTIR. Its polymerization has been investigated and monitored by DSC showing the ring opening polymerization of benzoxazine functions with a network densification thanks to the reaction of the furan group. The high hydroxyl content of the monomer allows its easy solubilisation in water paving the way to a wide range of possible environmentally friendly applications especially in the fields of coatings, paintings and adhesives.
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