期刊
GREEN CHEMISTRY
卷 18, 期 1, 页码 144-149出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5gc01884f
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资金
- UGC (University Grant Commission) India, New Delhi
A green and highly efficient protocol for the synthesis of 1,3,5-triazines from benzylamines and N-substituted benzylamines with amidines in PEG-600 has been developed. This protocol is transition-metal free, phosphine ligand free and uses inexpensive, easily available molecular oxygen (O-2) as an oxidant. A series of 1,3,5-triazines derivatives were synthesized in good to excellent yields in a shorter reaction time. The ease of the product separation and reusability of PEG-600 makes it more environmentally benign and economically affordable for gram-scale synthesis.
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