期刊
GREEN CHEMISTRY
卷 18, 期 4, 页码 932-936出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5gc02633d
关键词
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资金
- National Science Foundation of China [21202049]
- Recruitment Program of Global Experts (1000 Talents Plan) and Fujian Hundred Talents Plan
- Program of the Innovative Research Team of Huaqiao University
A transition-metal-free synthesis of alkylboronates, utilizing arylacetylenes or vinyl arenes and bis(pinacolato) diboron through tandem borylation and protodeboronation, has been developed. This reaction is efficient, practical and environmentally benign, leading to anti-Markovnikov products with excellent regioselectivity, broad functional group tolerance and excellent yields in both small and gram scales.
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