期刊
GREEN CHEMISTRY
卷 18, 期 12, 页码 3577-3581出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6gc00579a
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资金
- Energy Biosciences Institute
Self-condensation of biomass-derived methyl ketones catalyzed by solid bases or acids produces corresponding cyclic trimers exclusively in excellent yields. Condensates containing 24-45 carbon atoms are shown to be suitable lubricant base-oils after the removal of residual unsaturation and oxygen. Properties of cycloalkanes produced from biomass are very similar to those of conventional lubricant base-oils. The process reported here offers an environmentally benign alternative to the current non-selective production of lubricant base-oils from a-olefins, and avoids the production of corrosive waste products.
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