期刊
ACS APPLIED ENERGY MATERIALS
卷 4, 期 6, 页码 6356-6363出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.1c01256
关键词
potassium-ion battery; anode; CoSe; hollow structure; double-layer carbon protection
资金
- Natural Science Foundation of Jiangsu Province of China [BK20180086]
The study introduces a novel carbon-coated CoSe hollow nano-capsules for potassium-ion batteries, showing promising electrochemical performance. The material exhibits high reversible capacity, excellent rate capability, and good cycling stability. Furthermore, a full potassium-ion battery using P2-type K0.6CoO2 as cathode material also demonstrates improved electrochemical performance.
Research on potassium-ion batteries (PIBs) has recently been reemphasized because of the irreplaceable advantages of abundant resource, cheap price, and comparable standard redox potential to lithium, displaying great potential for large-scale energy conversion. Nevertheless, the development of PIBs is tremendously hindered due to the shortage of matching electrode materials that can reversibly uptake/release larger K+ during discharging and charging. Herein, we report the fabrication of double-layer carbon-coated CoSe hollow nano-capsules (denoted as CoSe@C/HCPs) using a flexible template-assisted strategy. The as-prepared CoSe@C/HCPs exhibit enhanced electrochemical performance as an anode material for PIBs. In particular, they can deliver a high reversible capacity of 461 mAh g(-1) at 100 mA g(-1), an extraordinary rate capability of 278 mAh g(-1) at 3 A g(-1), and decent cycling stability with 182 mAh g-1 retained at 3 A g(-1) after 300 cycles. More importantly, a full PIB cell (P2-type K0.6CoO2 used as the cathode material) also demonstrates an improved electrochemical performance (168 mAh g(-1) at 100 mA g(-1) after 100 cycles). These current studies have made a vanguard attempt to synthesize selenium-based anodes with sophisticated hierarchical architectures for PIBs, which could provide extensive impetus for the evolution of advanced PIBs.
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