High-Performance Lithium Metal Batteries with a Wide Operating Temperature Range in Carbonate Electrolyte by Manipulating Interfacial Chemistry

Article Chemistry, Multidisciplinary

Regulating Interfacial Chemistry in Lithium-Ion Batteries by a Weakly Solvating Electrolyte**

Yu-Xing Yao et al.

Summary: The research reveals a weakly solvating electrolyte that improves the performance of Li-ion batteries by forming unique anion-derived interfaces, demonstrating fast-charging and long-term cycling characteristics.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

An Inorganic-Rich Solid Electrolyte Interphase for Advanced Lithium-Metal Batteries in Carbonate Electrolytes

Sufu Liu et al.

Summary: In this study, an inorganic-rich solid electrolyte interphase (SEI) was designed on the Li-metal surface in carbonate electrolytes to reduce the bonding energy with Li metal, enabling high Li plating/stripping efficiency and cycling performance. The weak bonding of the SEI to Li promotes Li diffusion and prevents Li dendrite penetration, resulting in a high Coulombic efficiency during cycling.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Gradient Solid Electrolyte Interphase and Lithium-Ion Solvation Regulated by Bisfluoroacetamide for Stable Lithium Metal Batteries

Fang Li et al.

Summary: This study focuses on the impact of bisfluoroacetamide (BFA) as an electrolyte additive on the solid electrolyte interphase (SEI) structure. By constructing a gradient SEI structure, it achieves better Li ion capture and transportation effects.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Endogenous Symbiotic Li3N/Cellulose Skin to Extend the Cycle Life of Lithium Anode

Yang Luo et al.

Summary: Nitrocellulose (NC) is proposed as a stabilizer for electrolytes in Li metal batteries, forming a bilayer structure that promotes uniform lithium ion deposition and inhibits dendrite growth, leading to a significant increase in cycle life compared to batteries without NC.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Chemistry, Physical

A Growing Appreciation for the Role of LiF in the Solid Electrolyte Interphase

Jian Tan et al.

Summary: Rechargeable lithium batteries have transformed energy storage technology, but their further commercialization is hindered by short lifetime and safety issues, mainly due to the unstable solid-electrolyte interphase (SEI) and uncontrolled lithium dendrite growth. Research on SEI worldwide has focused on its debated structure and composition, particularly the role of the main component LiF. This review covers the development history of the SEI model, fundamental understanding of SEI, categorization of anode materials generating LiF in SEI, characterization techniques of SEI layers, transport mechanism of Li+ ions within SEI, physical properties of LiF, and analysis of LiF sources, offering insights for future research directions to promote large-scale applications of lithium metal batteries.

ADVANCED ENERGY MATERIALS (2021)

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Article Materials Science, Multidisciplinary

In situ protection of a sulfur cathode and a lithium anode via adopting a fluorinated electrolyte for stable lithium-sulfur batteries

Xue Chen et al.

Summary: A novel fluorinated electrolyte has been developed for Li-S batteries, which can prevent the dissolution of LiPS, restrict Li dendrite growth, and exhibit fire resistance, offering a new approach for developing high-safety and long-life Li-S batteries.

SCIENCE CHINA-MATERIALS (2021)

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Article Chemistry, Physical

Cooperative stabilization of bi-electrodes with robust interphases for high-voltage lithium-metal batteries

Qianqian Liu et al.

Summary: The addition of PFPN additive in high-voltage Li-metal batteries helps to stabilize the reaction mechanisms between the lithium metal anode and high-voltage cathodes by forming protective interphase layers, resulting in improved cycling stability and rate capability of the batteries.

ENERGY STORAGE MATERIALS (2021)

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Article Materials Science, Multidisciplinary

Realizing poly(ethylene oxide) as a polymer for solid electrolytes in high voltage lithium batteries via simple modification of the cell setup

Lukas Stolz et al.

Summary: Pure PEO-based solid polymer electrolyte is often considered unsuitable for high voltage applications in Li metal batteries due to destructive failure caused by short circuits during dendrite penetration. This failure can be prevented by increasing electrode distance or incorporating a spacer to enable stable operation and fulfill benchmark standards in systematic R&D.

MATERIALS ADVANCES (2021)

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Review Chemistry, Multidisciplinary

Insights into the deposition chemistry of Li ions in nonaqueous electrolyte for stable Li anodes

Zhenxing Wang et al.

Summary: Lithium (Li) is considered the best choice for high energy density energy storage systems, but uncontrollable dendrite formation causes safety concerns and poor coulombic efficiency. This review focuses on the factors influencing dendrite evolution, from formation to growth, in order to understand deposition chemistry better. Special attention is given to the effects of various factors on Li+ movement, desolvation, solid electrolyte interphase formation, and diffusion coefficient, with recommendations for reducing side reactions and volume expansion.

CHEMICAL SOCIETY REVIEWS (2021)

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Article Materials Science, Multidisciplinary

Designing electrolytes for lithium metal batteries with rational interface stability

Chen-Xuan Xu et al.

RARE METALS (2021)

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Article Chemistry, Multidisciplinary

Enabling High-Voltage Lithium Metal Batteries by Manipulating Solvation Structure in Ester Electrolyte

Yulin Jie et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

High Interfacial-Energy Interphase Promoting Safe Lithium Metal Batteries

Sufu Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Review Chemistry, Physical

Fundamentals and Challenges of Lithium Ion Batteries at Temperatures between-40 and 60 °C

Junbo Hou et al.

ADVANCED ENERGY MATERIALS (2020)

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Review Chemistry, Multidisciplinary

Advanced Liquid Electrolytes for Rechargeable Li Metal Batteries

Yulin Jie et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Synergistic Dual-Additive Electrolyte Enables Practical Lithium-Metal Batteries

Siyuan Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Cycling a Lithium Metal Anode at 90 °C in a Liquid Electrolyte

Li-Peng Hou et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Physical

Adsorption Preference of HF over Ethylene Carbonate Leads to Dominant Presence of Fluoride Products in LiFePO4 Cathode- Electrolyte Interface in Li-Ion Batteries

Arihant Bhandari et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

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Article Multidisciplinary Sciences

Poly(Ethylene Oxide)-based Electrolyte for Solid-State-Lithium-Batteries with High Voltage Positive Electrodes: Evaluating the Role of Electrolyte Oxidation in Rapid Cell Failure

Gerrit Homann et al.

SCIENTIFIC REPORTS (2020)

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Article Chemistry, Physical

An All-Fluorinated Ester Electrolyte for Stable High-Voltage Li Metal Batteries Capable of Ultra-Low-Temperature Operation

John Holoubek et al.

ACS ENERGY LETTERS (2020)

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Review Chemistry, Physical

Electrolyte-Additive-Driven Interfacial Engineering for High-Capacity Electrodes in Lithium-Ion Batteries: Promise and Challenges

Koeun Kim et al.

ACS ENERGY LETTERS (2020)

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Article Chemistry, Physical

Efficient Low-Temperature Cycling of Lithium Metal Anodes by Tailoring the Solid-Electrolyte Interphase

Akila C. Thenuwara et al.

ACS ENERGY LETTERS (2020)

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Article Energy & Fuels

Low-temperature and high-rate-charging lithium metal batteries enabled by an electrochemically active monolayer-regulated interface

Yue Gao et al.

NATURE ENERGY (2020)

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Article Chemistry, Multidisciplinary

Effective Optimization of High Voltage Solid-State Lithium Batteries by Using Poly(ethylene oxide)-Based Polymer Electrolyte with Semi-Interpenetrating Network

Gerrit Homann et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Enabling Stable High-Voltage LiCoO2Operation by Using Synergetic Interfacial Modification Strategy

Xuerui Yang et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Lithium Nitrate Regulated Sulfone Electrolytes for Lithium Metal Batteries

Jiale Fu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Chemistry, Physical

Designing Advanced Lithium-Based Batteries for Low-Temperature Conditions

Abhay Gupta et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Multidisciplinary Sciences

Interface chemistry of an amide electrolyte for highly reversible lithium metal batteries

Qidi Wang et al.

NATURE COMMUNICATIONS (2020)

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Review Chemistry, Physical

Rechargeable Battery Electrolytes Capable of Operating over Wide Temperature Windows and Delivering High Safety

Xidong Lin et al.

ADVANCED ENERGY MATERIALS (2020)

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Review Chemistry, Multidisciplinary

Lithium Metal Anodes with Nonaqueous Electrolytes

Ji-Guang Zhang et al.

CHEMICAL REVIEWS (2020)

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Article Chemistry, Physical

Polymer-inorganic solid-electrolyte interphase for stable lithium metal batteries under lean electrolyte conditions

Yue Gao et al.

NATURE MATERIALS (2019)

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Review Energy & Fuels

Advances and issues in developing salt-concentrated battery electrolytes

Yuki Yamada et al.

NATURE ENERGY (2019)

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Article Energy & Fuels

Improving cyclability of Li metal batteries at elevated temperatures and its origin revealed by cryo-electron microscopy

Jiangyan Wang et al.

NATURE ENERGY (2019)

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Article Energy & Fuels

Monolithic solid-electrolyte interphases formed in fluorinated orthoformate-based electrolytes minimize Li depletion and pulverization

Xia Cao et al.

NATURE ENERGY (2019)

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Article Chemistry, Multidisciplinary

Distinct Nanoscale Interphases and Morphology of Lithium Metal Electrodes Operating at Low Temperatures

Akila C. Thenuwara et al.

NANO LETTERS (2019)

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Article Energy & Fuels

All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents

Xiulin Fan et al.

NATURE ENERGY (2019)

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Review Chemistry, Multidisciplinary

Recent Advances in Energy Chemistry between Solid-State Electrolyte and Safe Lithium-Metal Anodes

Xin-Bing Cheng et al.

CHEM (2019)

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Review Chemistry, Physical

Fluorinated Solid-Electrolyte Interphase in High-Voltage Lithium Metal Batteries

Tao Li et al.

JOULE (2019)

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Review Energy & Fuels

Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries

Paul Albertus et al.

NATURE ENERGY (2018)

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Article Chemistry, Physical

Triphenylphosphine Oxide as Highly Effective Electrolyte Additive for Graphite/NMC811 Lithium Ion Cells

Kolja Beltrop et al.

CHEMISTRY OF MATERIALS (2018)

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Review Chemistry, Multidisciplinary

Interfaces and Materials in Lithium Ion Batteries: Challenges for Theoretical Electrochemistry

Johannes Kasnatscheew et al.

TOPICS IN CURRENT CHEMISTRY (2018)

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Article Chemistry, Multidisciplinary

Lithium Nitrate Solvation Chemistry in Carbonate Electrolyte Sustains High-Voltage Lithium Metal Batteries

Chong Yan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Article Multidisciplinary Sciences

Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery

Xiulin Fan et al.

SCIENCE ADVANCES (2018)

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Article Electrochemistry

A Tutorial into Practical Capacity and Mass Balancing of Lithium Ion Batteries

Johannes Kasnatscheew et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2017)

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Article Multidisciplinary Sciences

Liquefied gas electrolytes for electrochemical energy storage devices

Cyrus S. Rustomji et al.

SCIENCE (2017)

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Review Chemistry, Multidisciplinary

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review

Xin-Bing Cheng et al.

CHEMICAL REVIEWS (2017)

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Article Chemistry, Physical

The truth about the 1st cycle Coulombic efficiency of LiNi1/3Co1/3Mn1/3O2 (NCM) cathodes

J. Kasnatscheew et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2016)

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Article Electrochemistry

Additives for stabilizing LiPF6-based electrolytes against thermal decomposition

WT Li et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2005)

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Article Chemistry, Physical

Hexamethylphosphoramide as a flame retarding additive for lithium-ion battery electrolytes

S Izquierdo-Gonzales et al.

JOURNAL OF POWER SOURCES (2004)

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Review Chemistry, Multidisciplinary

Nonaqueous liquid electrolytes for lithium-based rechargeable batteries

K Xu

CHEMICAL REVIEWS (2004)

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High-Performance Lithium Metal Batteries with a Wide Operating Temperature Range in Carbonate Electrolyte by Manipulating Interfacial Chemistry

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