期刊
FRONTIERS IN CHEMISTRY
卷 9, 期 -, 页码 -出版社
FRONTIERS MEDIA SA
DOI: 10.3389/fchem.2021.703561
关键词
organic solar cell; electron transporting layer; perylene diimide derivative; tin oxide; surface defects
资金
- Foundation of National Natural Science Foundation of China (NSFC) [61421002, 61675041, 51703019]
- Sichuan Science and Technology Program [2019YFG0121, 2019YJ0178, 2020YFG0279, 2020YFG0281]
- Sichuan Provincial Key Laboratory of Display Science and Technology
Introducing the perylene diimide derivative PDINO successfully eliminated defects between the tin oxide nanoparticles electron transporting layer and the active layer, significantly improving the power conversion efficiency of organic solar cells.
Recently, tin oxide (SnO2) nanoparticles (NPs) have attracted considerable attention as the electron transporting layer (ETL) for organic solar cells (OSCs) due to their superior electrical properties, excellent chemical stability, and compatibility with low-temperature solution fabrication. However, the rough surface of SnO2 NPs may generate numerous defects, which limits the performance of the OSCs. In this study, we introduce a perylene diimide derivative (PDINO) that could passivate the defects between SnO2 NP ETL and the active layer. Compared with the power conversion efficiency (PCE) of the pristine SnO2 ETL-based OSCs (12.7%), the PDINO-modified device delivers a significantly increased PCE of 14.9%. Overall, this novel composite ETL exhibits lowered work function, improved electron mobility, and reduced surface defects, thus increasing charge collection efficiency and restraining defect-caused molecular recombination in the OSC. Overall, this work demonstrates a strategy of utilizing the organic-inorganic hybrid ETL that has the potential to overcome the drawbacks of SnO2 NPs, thereby developing efficient and stable OSCs.
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