Atomic-scale insights into ω-variants in Galfenol triggered by displacive-diffusive transformation

Galfenol owing excellent deformation due to lattice softening are regarded as a new generation of smart magnetostrictive materials. However, the lack of direct probes of phase transformation and intermediate phase related to lattice softening blocks the comprehensive understanding of their intrinsic magnetostrictive mechanism and further improvement of their performance. In this work, we firstly report an atomic observation of omega phase transformation in Galfenol under low temperature aging by spherical aberration-corrected transmission electron microscopy. The omega precipitates with two variants are directly probed to be decomposed from FeGa bcc matrix with the assistances of both spinodal decomposition and displacive transformation. Their orientation relationships with the long range ordered bcc structure of D0(3) can be well indexed into (0003)(omega 1)[11 (2) over bar0](omega 1) parallel to (4 (4) over bar(4) over bar)(D03)[0 (1) over tilde1](D03) parallel to ((4) over bar 40 (1) over bar)(omega 2)[11 (2) over bar0](omega 2). Density functional theory calculations unveil the precipitate of omega phase in Galfenol is theoretically possible. Further magnetostrictive measurements reveal the omega phase precipitates deteriorate the magnetostriction of Galfenol as empirically expected. Our work is believed to contribute a further insight of precipitate and structural evolution in Galfenol and is significant to maintain the magnetostriction performance of Galfenol in service. (C) 2021 The Author(s). Published by Elsevier Ltd.

Automated summary

In this study, omega phase transformation in Galfenol under low temperature aging was observed, and it was found that the omega phase precipitates deteriorate the magnetostriction of Galfenol. This provides important insights into the structural evolution of Galfenol and its magnetostrictive performance.