期刊
SCIENCE BULLETIN
卷 67, 期 2, 页码 171-177出版社
ELSEVIER
DOI: 10.1016/j.scib.2021.09.013
关键词
Photo-stability; Work function; Cathode interlayer; Hyperbranched polymer; Organic solar cell
资金
- National Natural Science Foundation of China [52173189, 22105208]
In this study, a novel reaction-inert material PDIEIE was designed and synthesized, which effectively improved the interface stability between the indium tin oxide electrode and photoactive materials, significantly enhancing the photo-stability performance of OSC devices.
Device stability becomes one of the most crucial issues for the commercialization of organic solar cells (OSCs) after high power conversion efficiencies have been achieved. Besides the intrinsic stability of photoactive materials, the chemical/catalytic reaction between interfacial materials and photoactive materials is another critical factor that determines the stability of OSC devices. Herein, we design and synthesize a reaction-inert rylene diimide-embedded hyperbranched polymer named as PDIEIE, which effectively reduces the work function of indium tin oxide electrode from 4.62 to 3.65 eV. Meanwhile, PDIEIE shows negligible chemical reaction with high-performance photoactive materials and no catalytic effect under strong ultraviolet illumination, resulting in much better photo-stability of OSCs with PDIEIE cathode interlayer (CIL), relative to the traditional CILs, including most-widely used metal oxides and polyethyleneimine derivatives. (c) 2021 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据