期刊
SCIENCE BULLETIN
卷 67, 期 1, 页码 71-78出版社
ELSEVIER
DOI: 10.1016/j.scib.2021.08.001
关键词
Dual catalysis; Polymeric carbon nitride; Heterogeneous photocatalysis; C-H functionalization; C-N coupling
资金
- National Natural Science Foun-dation of China [21972094, 21805191]
- Guangdong Special Support Program, Pengcheng Scholar Program, China Postdoctoral Science Foundation [2019M653004]
- Shenzhen Peacock Plan [KQTD2016053112042971]
- Shenzhen Science and Technology Program [JCYJ20190808142001745, JCYJ20200812160737002, RCJC20200714114434086]
- Guangdong Basic and Applied Basic Research Foundation [2020A1515010982]
A combination of copper catalysis and semiconductor photocatalysis using polymeric carbon nitride (PCN) was developed for multi-type cross-coupling reactions. This dual-catalytic system enables mild C-H arylation, chalcogenation, and C-N cross-coupling reactions under visible light irradiation with a broad substrate scope. The metal-free and low-cost PCN photocatalyst can be easily recovered and reused multiple times, showing good yields and functional group tolerance.
A merger of copper catalysis and semiconductor photocatalysis using polymeric carbon nitride (PCN) for multi-type cross-coupling reactions was developed. This dual-catalytic system enables mild C-H arylation, chalcogenation, and C-N cross-coupling reactions under visible light irradiation with a broad substrate scope. Good-to-excellent yields were obtained with appreciable site selectivity and functional group tolerance. Metal-free and low-cost PCN photocatalyst can easily be recovered and reused several times. (c) 2021 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
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