A wrinkled ZnO/MCM-41 nanocomposite: hydrothermal synthesis and characterization

ZnO/MCM-41 composites consisting of loose particles with an irregular, wrinkled surface and flower-like morphology were obtained by adding MCM-41 to a mixture of zinc nitrate hexahydrate and hexamethylenetetramine under hydrothermal conditions. The physical properties of this composite were determined by scanning electron microscopy (SEM), x-ray powder diffraction (XRD), Fourier Transform Infrared spectroscopy (FTIR), and photoluminescence spectroscopy (PL). The XRD analysis showed the characteristic diffractogram corresponding to silica overlapped with ZnO peaks, with a reduction in the sharpness and peak intensity, which may be the result of spatial disorder and defects, combined with anisotropic preferential growth. The FTIR spectrum had the characteristic vibrations expected for a silica framework, containing adsorbed water molecules, nitrate ions, and Zn-O bonds. This novel structure may be of particular interest from both fundamental and applied perspectives. It can be advantageous for the adsorption and capture of small molecules. Therefore, it may improve the performance of some previously investigated uses for these ZnO/MCM-41composites, such as photocatalysis and adsorbents for pollutants removal. To the best of our knowledge, this is the first time that wrinkled ZnO/MCM-41 nanocomposite obtained by a low-cost and easy method is reported.

Automated summary

The ZnO/MCM-41 composites with flower-like morphology and wrinkled surface were successfully synthesized via a low-cost and easy method under hydrothermal conditions. The composite showed unique physical properties, such as irregular structure and adsorption capabilities, making it potentially beneficial for applications in photocatalysis and pollutant removal. This novel structure may provide insights for further research and development in the field of nanocomposite materials.