Facile Synthesis of MoP-RuP2 with Abundant Interfaces to Boost Hydrogen Evolution Reactions in Alkaline Media

Exploiting efficient electrocatalysts for hydrogen evolution reactions (HERs) is important for boosting the large-scale applications of hydrogen energy. Herein, MoP-RuP2 encapsulated in N,P-codoped carbon (MoP-RuP2@NPC) with abundant interfaces were prepared via a facile avenue with the low-toxic melamine phosphate as the phosphorous resource. Moreover, the obtained electrocatalyst possessed a porous nanostructure, had abundant exposed active sites and improved the mass transport during the electrocatalytic process. Due to the above merits, the prepared MoP-RuP2@NPC delivered a greater electrocatalytic performance for HERs (50 mV@10 mA cm(-2)) relative to RuP2@NPC (120 mV) and MoP@NPC (195 mV) in 1 M KOH. Moreover, an ultralow potential of 1.6 V was required to deliver a current density of 10 mA cm(-2) in the two-electrode configuration for overall water splitting. For practical applications, intermittent solar energy, wind energy and thermal energy were utilized to drive the electrolyzer to generate hydrogen gas. This work provides a novel and facile strategy for designing highly efficient and stable nanomaterials toward hydrogen production.

Automated summary

This study demonstrates a novel and facile strategy for designing highly efficient and stable nanomaterials for hydrogen production by preparing MoP-RuP2@NPC electrocatalyst with porous nanostructure and abundant active sites. Compared to other materials, MoP-RuP2@NPC shows superior electrocatalytic performance for hydrogen evolution reactions. Furthermore, intermittent solar energy, wind energy, and thermal energy were successfully utilized to drive the electrolyzer for hydrogen gas generation.