Solvent-Free Mechanochemical Synthesis and Characterization of Nickel Tellurides with Various Stoichiometries: NiTe, NiTe2 and Ni2Te3

The paper reports the synthesis of nickel tellurides via a mechanochemical method from elemental precursors. NiTe, NiTe2, and Ni2Te3 were prepared by milling in stainless steel vials under nitrogen, using milling times from 1 h to 12 h. The products were characterized by powder X-ray diffraction (pXRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), dynamic light scattering (DLS), vibrating sample magnetometer (VSM), UV-VIS spectrometry, and thermal analysis (TGA and DSC). The products were obtained in the form of aggregates, several hundreds of nanometers in size, consisting of smaller nanosized crystallites. The magnetic measurements revealed a ferromagnetic behavior at room temperature. The band gap energies calculated using Tauc plots for NiTe, NiTe2, and Ni2Te3 were 3.59, 3.94, and 3.70 eV, respectively. The mechanochemical process has proved to be a simple and successful method for the preparation of binary nickel tellurides, avoiding the use of solvents, toxic precursors, and energy-consuming reaction conditions.

Automated summary

Binary nickel tellurides NiTe, NiTe2, and Ni2Te3 were successfully synthesized via a mechanochemical method, with the products characterized using various techniques. The materials exhibited nanostructured aggregates with ferromagnetic behavior and band gap energies calculated from Tauc plots.