期刊
MINERALS
卷 11, 期 8, 页码 -出版社
MDPI
DOI: 10.3390/min11080805
关键词
Grenvillian orogeny; Oaxacan Complex; garnet main end members; minor and trace elements; garnet geothermobarometry; structural levels
资金
- CONACYT [240226]
- DGAPA-UNAM [IN111917]
This study investigates garnets from the southwestern Oaxacan Complex in Mexico for the first time, providing insights into their petrographical, geochemical, and geothermobarometrical characteristics. The results show that the garnets in different lithotypes have similar almandine proportions but differ in pyrope concentrations and element enrichments. The pressure obtained in this study is higher than in the northern part of the Complex, indicating different structural levels within the orogen.
The basement of eastern Mexico comprises Grenvillian-age granulite-facies metamorphic rocks. The Oaxacan Complex represents the largest outcrop belt of this basement in Mexico. In this work, southwestern Oaxacan Complex garnets are studied from a petrographical, geochemical, and geothermobarometrical perspective for the first time. The studied garnets display different grain sizes nucleated in a polyphase evolution. The almandine end member proportion is similar in all of the studied lithotypes. The highest pyrope concentrations are found in Qz Fsp paragenesis and ultramafic rocks and the lowest pyrope concentrations are found in amphibolite. The highest grossular and spessartine concentrations are found in the amphibolite lithotype. Southwestern Oaxacan Complex garnets from paraderivate samples are more enriched in Rb, Ba, Pb, Ni, and Zn than those from orthoderivate samples enriched in Ti and V. This fact is related to the nature of the protoliths and the mineral phases that fractionate the same minor and trace elements. Garnets from para- and orthoderivate samples display 0.02-1.1 Eu/Eu* anomalies. This fact indicates that almost all of the garnets formed while the plagioclase was stable, and it does not rule out the interpretation that some garnets were peritectic. The pressure obtained using a Grt-Opx-Pl-Qz geobarometer in the southwestern Oaxacan Complex is higher than the pressure obtained in the northern part of the Complex, and it is consistent with the pressure obtained in the Grenvillian-age granulites of the Novillo Gneiss from northeastern Mexico. Geothermobarometric studies reveal different P-T features at the study site, so different structural levels of the orogen are inferred.
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