4.5 Article

Optimization Studies on Biological Desulfurization of Sulfide Ore Using Response Surface Methodology

期刊

MINERALS
卷 11, 期 6, 页码 -

出版社

MDPI
DOI: 10.3390/min11060583

关键词

Acidithiobacillus caldus; spontaneous combustion; biodesulfurization; sulfide ore

资金

  1. National Key R&D Program of China [2018YFC1801804]
  2. National Natural Science Foundation of China [51504298]
  3. Natural Science Foundation of Hunan Province [2017JJ3160]

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This research optimized the experimental conditions for biodesulfurization of sulfide ore, resulting in a significant increase in desulfurization efficiency and a reduction in the oxidizability and spontaneous combustion tendency of the ore after desulfurization.
This research aimed to optimize the experimental conditions of biodesulfurization of sulfide ore and to evaluate the flame-retardant effect after desulfurization under optimal conditions. Six experimental factors were determined: particle size of ore sample, ambient temperature, rotary speed of the shaking table, volume of bacteria liquid, concentration of leaching aid (Tween80), and pH value of acidizing ore sample. Desulfurization efficiency was used as the main characterization index of the desulfurization effect in optimization studies. Particle size of ore sample, rotary speed of the shaking table, and volume of bacteria liquid inoculated were selected as significant factors by a Plackett-Burman experiment. Modeling, optimization, and analysis of the interactive effects of these factors, notably between particle size and bacteria liquid, were performed using a Box-Behnken design with response surface methodology. The optimum operating conditions were found to be: particle size of 120 to 140 mesh, rotary speed of 175 rpm, and bacteria liquid of 111 mL. Under these conditions, a significant rise of 8.1% was seen in 5-day average desulfurization efficiency. The 5-day oxidation weight gain rate of desulfurized ore was 2.73%, while that of the control group was 4.78%. The results show that, after optimized desulfurization, the surface oxidizability and spontaneous combustion tendency of the ore are reduced.

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