Studies of Nickel/Samarium-Doped Ceria for Catalytic Partial Oxidation of Methane and Effect of Oxygen Vacancy

We investigated the performance of nickel/samarium-doped ceria (Ni/SDC) nanocatalysts on the catalytic partial oxidation of methane (CPOM). Studies of temperature-programmed surface reaction and reduction reveal that catalytic activity is determined by a synergistic effect produced by Ni metals and metal-support interaction. Catalytic activity was more dependent on the Ni content below 600 degrees C, while there is not much difference for all catalysts at high temperatures. The catalyst exhibiting high activities toward syngas production (i.e., a CH4 conversion >90% at 700 degrees C) requires a medium Ni-SDC interaction with an Sm/Ce ratio of about 1/9 to 2/8. This is accounted for by optimum oxygen vacancies and adequate ion diffusivity in the SDCs which, as reported, also display the highest ion conductivity for fuel cell applications.

Automated summary

The study revealed that catalytic activity is determined by the interaction between Ni metals and the metal-support, with activity being more dependent on Ni content at lower temperatures. For catalysts at high temperatures, there is not much difference in activity. Catalysts with high syngas production require a medium Ni-SDC interaction, with optimal oxygen vacancies and ion diffusivity in the SDCs.