期刊
CHEMISTRYOPEN
卷 11, 期 2, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/open.202100145
关键词
bismuth; heterocubanes; ionic liquids; ionothermal synthesis; spirocubanes
资金
- Deutsche Forschungsgemeinschaft (DFG) [SPP 1708]
Bi2S3 was dissolved in an ionic liquid [BMIm]Cl in the presence of NaCl, resulting in the formation of a complex crystal structure containing various structural units such as (Bi7S8)(5+) spiro-dicubanes and [S(AlCl3)(3)](2-) tetrahedra triples.
Bi2S3 was dissolved in the presence of NaCl in the ionic liquid [BMIm]Cl . 4AlCl(3) (BMIm=1-n-butyl-3-methylimidazolium) through annealing the mixture at 180 degrees C. Upon cooling to room temperature, orange, air-sensitive crystals of Na(Bi7S8)[S(AlCl3)(3)](2)[AlCl4](2) (1) precipitated. X-ray diffraction on single-crystals of 1 revealed a triclinic crystal structure that contains (Bi7S8)(5+) spiro-dicubanes, [S(AlCl3)(3)](2-) tetrahedra triples, isolated [AlCl4](-) tetrahedra, and sodium cations.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据