期刊
ASIAN JOURNAL OF ORGANIC CHEMISTRY
卷 10, 期 8, 页码 2220-2230出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.202100314
关键词
Bio-electrolytes; Redox electrolytes; Pivalic acid; Ascorbic Acid; Activated carbon; Electrochemical Energy Storage
资金
- CENT-KFUPM
- Bangladesh University of Engineering and Technology (BUET)
- University Grants Commission (UGC)
- Ministry of Science and Technology (MoST), Bangladesh
This study reports the development of a novel redox bio-electrolyte based on pivalic acid and ascorbic acid for supercapacitors, which demonstrates high performance and aims to broaden the application of bio-based redox electrolytes in practical energy storage applications.
Supercapacitor is considered a promising energy storage device due to its high-power density and high specific capacitance. Electrode materials and electrolytes are major components of supercapacitors. The most used electrolytes are not biocompatible, which limits their practical applications. Bio-electrolytes often cause low performances of supercapacitors. However, the inadequate performances of bio-electrolytes for supercapacitor applications could be improved using redox molecules. Here, we are reporting the development of a novel redox bio-electrolyte based on pivalic acid (PA) and ascorbic acid (AA). The salts of PA and AA served as the bio-electrolyte and redox molecules, respectively. It is worth to note that PA which can be generated from bio-sources and industrial wastes, is soluble in alkaline solutions. AA is found in most living organisms, including plants. The developed supercapacitor with the bio-based redox electrolyte provides a specific capacitance of 308 Fg(-1) at a current density of 1 Ag-1 and achieved an energy density of 15 Whkg(-1) at a power density of 300 Wkg(-1). The supercapacitor demonstrates a good coulombic efficiency of similar to 97% with capacitance retention of similar to 72% after 10000 charge-discharge cycles. This study is expected to widen the applications of bio-based redox electrolytes for practical electrochemical energy storage applications and enables access to greener and more sustainable energy storage technology.
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