4.6 Article

Sonoelectrochemistry: Ultrasound-assisted Organic Electrosynthesis

期刊

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 9, 期 29, 页码 9590-9603

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.1c02989

关键词

Organic sonoelectrosynthesis; Ultrasound; Heterogeneous catalysis; Sustainable chemistry; Synthetic sonoelectrochemistry and organic reaction engineering

资金

  1. Cardiff University
  2. Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior - Brasil (CAPES) [001]

向作者/读者索取更多资源

The combination of ultrasound and electrochemistry, known as organic sonoelectrochemistry, accelerates chemical reactions and enhances electrical efficiency and product yield. It helps in handling complex reaction systems and optimizing electrosynthetic processes.
The application of ultrasound with electrochemistry in organic chemistry (known as organic sonoelectrochemistry) accelerates the activation process of chemical reactions. This hybrid technology enhances electrical efficiency and modifies and increases the product yield. Moreover, it facilitates the mass transfer phenomena and the processes of cleaning, degassing, and activation of the electrode surfaces; maintains higher current densities for efficient chemical transformations; and also works efficiently for mixing of reactants in multiphase systems. The ultrasound technology has a prominent effect in heterogeneous reaction systems especially during the solid (electrode)-liquid (electrolytic mixture) interfacial cavitation process. The ultrasound technology gains attention due to its fundamental and positive effect in organic chemistry to make possible the challenging electrosynthetic processes. Herein, we report the sonoelectrosynthetic methods that will help researchers to understand and apply this methodology for scale-up of processes in organic synthesis and also in more modern innovative continuous-flow organic electrochemistry. Therefore, this study will provide valuable insight into the effects caused by ultrasound-assisted electrosynthesis and how this technology revolutionizes organic synthesis. It is believed that the hybrid sonoelectrochemical synthesis serves as a solution to the limitations of the commercialization of synthetic processes and offers a new, modern aspect in organic synthesis in a clean, hassle-free, and sustainable approach.

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