期刊
WATER
卷 13, 期 13, 页码 -出版社
MDPI
DOI: 10.3390/w13131724
关键词
bisphenol A; zero-valent iron; hydrogen peroxide; weak magnetic field; chloride
资金
- Open Project of Key Laboratory of Environmental Biotechnology, CAS
- National Natural Science Foundation of China [41807468, 22006093]
- Zhejiang Provincial Natural Science Foundation of China [LY18E080018]
- Natural Science Foundation of Shandong Province [ZR2020QB143]
- State Key Laboratory of Pollution Control and Resource Reuse Foundation [PCRRF18021]
- Taishan Scholar Program of Shandong Province [tsqn201909019]
- Qilu Young Scholar Program of Shandong University
- Shandong Provincial Key Research and Development Program (Major Scientific and Technological Innovation Project) [2019JZZY010411]
The study systematically investigated the coupling use of the heterogeneous Fenton-like process (zero-valent iron (Fe-0)/H2O2) and weak magnetic field (MWF) for bisphenol A (BPA) abatement. The results showed that the presence of Cl- as background ions significantly contributed to the generation of reactive chlorine species (RCS) and ClO3- in the process, while HCO3- played a role in diminishing the generation of ClO3-.
The coupling use of the heterogeneous Fenton-like process (zero-valent iron (Fe-0)/H2O2) and weak magnetic field (MWF) for bisphenol A (BPA) abatement was systematically investigated in this study. Though both the Fe-0/H2O2 and WMF-Fe-0/H2O2 processes are sensitive to pH, WMF remarkably enhanced BPA removal under the pH range of 3.0-6.0 by 0.5-9.5 times. The characterization of Fe-0 confirmed the role of WMF in promoting the corrosion of Fe-0. Radicals, rather than Fe intermediates, were responsible for BPA degradation. Due to the presence of Cl- as the background ions and its reactivity towards HO center dot, reactive chlorine species (RCS, i.e., Cl-center dot and Cl-2(center dot)) were produced and considerably contributed to BPA degradation. In addition, similar to 37% and 54% of degraded BPA was ascribed to RCS in the presence of 2 and 100 mM of Cl, respectively. However, 1.9 mg/L of ClO3- was detected in the presence of 2 mM of Cl- in the WMF-Fe-0/H2O2 process. HCO3- could diminish ClO3- generation significantly through transforming RCS. The concentration of ClO3- decreased by 74% and 82% with dosing 1 and 10 mM HCO3-, respectively. The results of this study suggest that the WMF-Fe-0/H2O2 process is a promising approach for BPA removal.
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