期刊
POLYMERS
卷 13, 期 15, 页码 -出版社
MDPI
DOI: 10.3390/polym13152440
关键词
PEEK; graphene; carbon fibre laminates; matrix-fibre interaction; nanoindentation; electrical conductivity; structure
资金
- Agencia Estatal de Investigacion (AEI) [MAT2017-88382-P]
- Fondo Europeo de Desarrollo Regional (FEDER, UE) [MAT2017-88382-P]
- Ministerio de Ciencia, Innovacion y Universidades (MCIU)
PEEK, as a promising candidate to replace epoxy resins in high-performance aeronautical applications, undergoes property optimization, including the interaction between fibers and the matrix. Incorporating modified graphene into the polymer layer results in a significant modulus improvement for the PEEK layer. Additionally, anisotropic electrical conductivity and high modulus values near the carbon fiber front are observed in the laminates.
PEEK appears as an excellent candidate to substitute epoxy resins in carbon fibre laminates for high-performance aeronautical applications. The optimization of the properties and, in particular, of the transition region between the fibres and the matrix appear as a major issue prior to serial production. Graphene, modified with two compatibilizers, has been incorporated in the polymer layer with the purpose of imparting additional functionalities and enhancing the matrix-fibre interaction. It is found that both carbon fibres and modified graphene significantly influence the crystallization behaviour and smaller, and/or more imperfect crystals appear while the degree of crystallinity decreases. Despite this, nanoindentation studies show that the PEEK layer exhibits significant modulus improvements (approximate to 30%) for 5 wt.% of graphene. Most importantly, the study of the local mechanical properties by nanoindentation mapping allows the identification of remarkably high modulus values close to the carbon fibre front. Such a relevant mechanical enhancement can be associated with the accumulation of graphene platelets at the polymer-fibre boundary, as revealed by electron microscopy studies. The results offer a feasible route for interlaminar mechanical improvement based on the higher density of graphene platelets at the fibre front that should promote interfacial interactions. Concerning electrical conductivity, a large anisotropy was found for all laminates, and values in the range similar to 10(-4) S/cm were found for the through-thickness arrangement as a consequence of the good consolidation of the laminates.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据