4.7 Article

Manipulating Crystallization for Simultaneous Improvement of Impact Strength and Heat Resistance of Plasticized Poly(l-lactic acid) and Poly(butylene succinate) Blends

期刊

POLYMERS
卷 13, 期 18, 页码 -

出版社

MDPI
DOI: 10.3390/polym13183066

关键词

poly(lactic acid); poly(butylene succinate); impact strength; annealing; crystallization; heat resistance

资金

  1. National Research Council of Thailand (NRCT) under the Research University Network Initiative

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The research focused on the impact of crystalline morphology and phase structure on the properties of polymer blends, showing that manipulating crystalline morphology through short-time annealing can affect impact toughness and thermal stability. By adding a plasticizer like poly(ethylene glycol) and heat treatment, a significant enhancement in impact strength and heat resistance of the blends can be achieved, demonstrating changes in fracture mechanism from crazing to shear yielding in the annealed samples.
Crystalline morphology and phase structure play a decisive role in determining the properties of polymer blends. In this research, biodegradable blends of poly(l-lactic acid) (PLLA) and poly(butylene succinate) (PBS) have been prepared by melt-extrusion and molded into specimens with rapid cooling. The crystalline morphology (e.g., crystallinity, crystal type and perfection) is manipulated by annealing the molded products from solid-state within a short time. This work emphasizes on the effects of annealing conditions on crystallization and properties of the blends, especially impact toughness and thermal stability. Phase-separation morphology with PBS dispersed particles smaller than 1 mu m is created in the blends. The blend properties are successfully dictated by controlling the crystalline morphology. Increasing crystallinity alone does not ensure the enhancement of impact toughness. A great improvement of impact strength and heat resistance is achieved when the PLLA/PBS (80/20) blends are plasticized with 5% medium molecular-weight poly(ethylene glycol), and simultaneously heat-treated at a temperature close to the cold-crystallization of PLLA. The plasticized blend annealed at 92 degrees C for only 10 min exhibits ten-fold impact strength over the starting PLLA and slightly higher heat distortion temperature. The microscopic study demonstrates the fracture mechanism changes from crazing to shear yielding in this annealed sample.

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