4.7 Article

Development and Characterization of Polypropylene Waste from Personal Protective Equipment (PPE)-Derived Char-Filled Sugar Palm Starch Biocomposite Briquettes

期刊

POLYMERS
卷 13, 期 11, 页码 -

出版社

MDPI
DOI: 10.3390/polym13111707

关键词

biopolymer composites; PPE; polypropylene; COVID-19 related waste; char briquette; sugar palm starch; pyrolysis

资金

  1. Ministry of Higher Education (MoHE) [5540346]
  2. Universiti Putra Malaysia, Malaysia

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This study focused on producing char briquettes from polypropylene powder derived from COVID-19 isolation gown waste, using sugar palm starch as a binder. The research showed that as the SPS loading increased, the compressive strength of the briquettes improved while the higher heating values decreased. The C-80/SPS-20 briquettes demonstrated excellent combustion characteristics and satisfactory mechanical strength, making them suitable for domestic and commercial uses.
Slow pyrolysis using a batch reactor at 450 degrees C was applied to the polypropylene (PP) powder derived from Coronavirus Disease 2019 (COVID-19) isolation gown waste to yield char briquettes, using sugar palm starch (SPS) and a manual hydraulic press. These studies are significant because of reductions in plastic waste from the preparation of barbecue coal due to environmental sustainability. The results presented here include the physical, morphological, thermal, combustion, and mechanical properties of char when reinforced with various percentages of SPS loadings (0, 10, 20, 30, and 40%), which act as a matrix/binder to produce char/sugar palm starch (C/SPS) composites. The physical and morphological characteristics of C/SPS composites were determined using Fourier transform infrared (FTIR) and field emission scanning electron microscopy (FESEM). On the other hand, the thermal and combustion properties of the C/SPS briquettes were studied via thermogravimetric and bomb calorimeter analysis. The results show that the compressive strength of the briquettes increased as the SPS loading increased, whereas the higher heating values (HHV) reduced. The findings indicate that C-80/SPS-20 briquettes presented excellent combustion characteristics (1,761,430 J/g) with satisfactory mechanical strength (1.463 MPa) in the compression test. Thus, C-80/SPS-20 briquettes are the most suitable composites for domestic and commercial uses.

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