期刊
POLYMERS
卷 13, 期 18, 页码 -出版社
MDPI
DOI: 10.3390/polym13183131
关键词
polypeptoids; diblock copolymers; crystallization; solution self-assembly
资金
- National Natural Science Foundation of China [52073025]
- Fundamental Research Funds for the Central Universities [FRF-IDRY-20-003]
- (Interdisciplinary Research Project for Young Teachers of USTB)
- National Science Foundation [CHE 2003458]
Polypeptoids, a class of synthetic peptidomimetic polymers, have the potential for biotechnological applications and can self-assemble into various nanostructures with tailorable morphologies and functionalities.
Polypeptoids, a class of synthetic peptidomimetic polymers, have attracted increasing attention due to their potential for biotechnological applications, such as drug/gene delivery, sensing and molecular recognition. Recent investigations on the solution self-assembly of amphiphilic block copolypeptoids highlighted their capability to form a variety of nanostructures with tailorable morphologies and functionalities. Here, we review our recent findings on the solutions self-assembly of coil-crystalline diblock copolypeptoids bearing alkyl side chains. We highlight the solution self-assembly pathways of these polypeptoid block copolymers and show how molecular packing and crystallization of these building blocks affect the self-assembly behavior, resulting in one-dimensional (1D), two-dimensional (2D) and multidimensional hierarchical polymeric nanostructures in solution.
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