Chemical Characterisation of Silanised Zirconia Nanoparticles and Their Effects on the Properties of PMMA-Zirconia Nanocomposites

Objectives: The objective of this study was to investigate the mechanical properties of high-impact (HI) heat-cured acrylic resin (PMMA) reinforced with silane-treated zirconia nanoparticles. Methods: Forty-five PMMA specimens reinforced with zirconia were fabricated and divided into three groups: Pure HI PMMA (control group), PMMA reinforced with 3 wt.% of non-silanised zirconia nanoparticles and PMMA reinforced with 3 wt.% of silanised zirconia nanoparticles. Silanised and non-silanised zirconia nanoparticles were analysed with Fourier Transform Infrared (FTIR) Spectroscopy. For measuring the flexural modulus and strength, a Zwick universal tester was used, and for surface hardness, a Vickers hardness tester were used. Furthermore, raw materials and fractured surfaces were analysed using Scanning Electron Microscopy (SEM). A one-way ANOVA test followed by a post-hoc Bonferroni test was employed to analyse the data. Results: The results showed that the mean values for flexural strength (83.5 +/- 6.2 MPa) and surface hardness (20.1 +/- 2.3 kg/mm(2)) of the group containing 3 wt.% treated zirconia increased significantly (p < 0.05) in comparison to the specimens in the group containing non-treated zirconia (59.9 +/- 7.1 MPa; 15.0 +/- 0.2 kg/mm(2)) and the control group (72.4 +/- 8.6 MPa; 17.1 +/- 0.9 kg/mm(2)). However, the group with silanised zirconia showed an increase in flexural modulus (2313 +/- 161 MPa) but was not significantly different (p > 0.05) from the non-silanised group (2207 +/- 252 MPa) and the control group (1971 +/- 235 MPa). Conclusion: Silane-treated zirconia nano-filler improves the surface hardness and flexural strength of HI PMMA-zirconia nanocomposites, giving a potentially longer service life of the denture base.

Automated summary

The study demonstrates that silane-treated zirconia nanoparticles significantly improve the surface hardness and flexural strength of high-impact heat-cured acrylic resin-zirconia nanocomposites.